5-phosphazenes)
owska-Trzebiatowska, Sofia Olejnik and Tadeusz Lis,
olig and Maja Penavi|
Letters H. Schäfer-Stahl, Dario Braga, Alberto Ripamonti, Diego Savoia, Claudio Trombini and Achille Umani-Ronchi, pp 328 DOI:10.1039/DT9810000328 |
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Back cover J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100BX003 |
Issue 2
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Front cover J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100FX005 |
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Contents pages J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100FP007 |
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Kinetics and mechanism of the decomposition of [(NH2)2CSNO]+ Peter Collings, Michael Garley and Geoffrey Stedman, pp 331 DOI:10.1039/DT9810000331 |
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Zinc complexes of four tetra-aza macrocycles: enthalpies of formation in acetonitrile solution Douglas P. Graddon, Mauro Micheloni and Piero Paoletti, pp 336 DOI:10.1039/DT9810000336 |
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Co-ordination chemistry of sulphines. Part 3. Oxidative addition of the carbon-chlorine bond of (E)-chloro(arylthio)-sulphine, (E)-(RS)CICSO, to tetrakis(triphenylphosphine) platinum(0) and of a carbon-sulphur bond in [Pt0(PPh3)2{(RS)2CSO}] by an intramolecular process. X-Ray crystal and molecular structure of cis-(E)-[PtII(PhS)(PhSCSO)(PPh3)2]·C6H6 Johan W. Gosselink, Gerard van Koten, Anja M. F. Brouwers and Ok Overbeek, pp 342 DOI:10.1039/DT9810000342 |
Mono- -cyclopentadienylmolybdenum chemistry: 1,2-bis(dimethylphosphino)ethane-hydrido, -halogeno, -alkyne, and -oxo derivativesGeorge S. B. Adams and Malcolm L. H. Green, pp 353 DOI:10.1039/DT9810000353 |
Reactivity of uranyl ion with quinquedentate chelating hydrazine derivatives. Part 3. 2,6-Diacetylpyridine (2 -pyridylhydrazone)(4 -toluoylhydrazone)Giampaolo Marangoni and Gino Paolucci, pp 357 DOI:10.1039/DT9810000357 |
Hydrolysis of  -amino-acid esters in mixed-ligand complexes with ethylenediaminepalladium(II)Robert W. Hay and Pradyot Banerjee, pp 362 DOI:10.1039/DT9810000362 |
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Novel compounds with gold-transition-metal bonds; crystal and molecular structure of bis(triphenylphosphine)iminium bis(tetracarbonylcobaltio)aurate(I) Rafael Usón, Antonio Laguna, Mariano Laguna, Peter G. Jones and George M. Sheldrick, pp 366 DOI:10.1039/DT9810000366 |
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The electronic structure of copper in the polymer potassium bis(carbonato)cuprate(II) as determined from precise X-ray diffraction data Brian N. Figgis, Philip A. Reynolds, Allan H. White and Geoffrey A. Williams, pp 371 DOI:10.1039/DT9810000371 |
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Complexes of organoaluminium compounds. Part 12. Preparation, nuclear magnetic resonance spectra, and the crystal and molecular structure of bis(µ-isopropylamido-dimethylaluminium) Saeid Amirkhalili, Peter B. Hitchcock, Aubrey D. Jenkins, (the late) Jeffery Z. Nyathi and J. David Smith, pp 377 DOI:10.1039/DT9810000377 |
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Preparation and the crystal and molecular structure of [NEt4][Ge{Co2(CO)7}{Co2(CO)6[HgCo(CO)4]}]: an anion containing a mercury-bridged cobalt-cobalt bond D. Neil Duffy, Kenneth M. Mackay, Brian K. Nicholson and Ward T. Robinson, pp 381 DOI:10.1039/DT9810000381 |
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Mechanism of cadmium and lead ion exchange by -zirconium bis-(monohydrogenorthophosphate) monohydrate Jai P. Gupta and Derek V. Nowell, pp 385 DOI:10.1039/DT9810000385 |
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Crystal structure studies of hydrazido(2-)quinolin-8-olato-complexes of molybdenum and tungsten Ian R. Hanson and David L. Hughes, pp 390 DOI:10.1039/DT9810000390 |
Reactions of co-ordinated ligands. Part 23. Metalla-ring-forming reactions between hexafluoroacetone and 4-1,3-diene(5-indenyl)rhodium complexes; the crystal and molecular structures of [Rh{OC(CF3)2CH2C(Me) CHCH2}(5-C9H7)] and [Rh{OC(CF3)2C3H3C6H4}(4-trans-C4H4Me2-1,4)]Peter Caddy, Michael Green, Judith A. K. Howard, Jacqueline M. Squire and Nicholas J. White, pp 400 DOI:10.1039/DT9810000400 |
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The preparation, characterisation, and some reactions of [Os3(CO)11-(NCMe)] Brian F. G. Johnson, Jack Lewis and David A. Pippard, pp 407 DOI:10.1039/DT9810000407 |
The structures of hypervalent phosphorus(III) anions P(CN)4-nBrn-. Transition from  -trigonal-bipyramidal to -octahedral co-ordination and deviation from Valence Shell Electron Pair Repulsion TheoryWilliam S. Sheldrick, Alfred Schmidpeter, Franz Zwaschka, Keith B. Dillon, Andrew W. G. Platt and Thomas C. Waddington, pp 413 DOI:10.1039/DT9810000413 |
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Redox potential-structure relationships in metal complexes. Part 3. The electrochemical activation of co-ordinated hydrazido(2-)-ligands Brian A. L. Crichton, Jonathan R. Dilworth, Christopher J. Pickett and Joseph Chatt, pp 419 DOI:10.1039/DT9810000419 |
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The molecular structures of difluorophosphino (disilyl)amine and bis-(difluorophosphino)silylamine in the gas phase, determined by electron diffraction Graham S. Laurenson and David W. H. Rankin, pp 425 DOI:10.1039/DT9810000425 |
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Spectrophotometric investigation of equilibria between silver(II) and 2,2-bipyridine Malcolm P. Heyward and Cecil F. Wells, pp 431 DOI:10.1039/DT9810000431 |
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The reaction of cysteine with the pentacyanonitrosylferrate(2-) ion Pedro J. Morando, Elena B. Borghi, Lydia M. de Schteingart and Miguel A. Blesa, pp 435 DOI:10.1039/DT9810000435 |
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Further studies on the spin cross-over phenomenon in di-isothiocyanatobis(1,10-phenanthroline)iron(II) Prabuddha Ganguli, Philipp Gütlich, E. Wolfgang Müller and Werner Irler, pp 441 DOI:10.1039/DT9810000441 |
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Polymer-supported oxobis(pentane-2,4-dionato)vanadium(IV) catalyst for reactions involving t-butyl hydroperoxide Sumit Bhaduri, Annoottam Ghosh and Hanif Khwaja, pp 447 DOI:10.1039/DT9810000447 |
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Ternary complexes of copper(I) with 2,9-dimethyl-1,10-phenanthroline and some oxygen-donor ligands Whei-Lu Kwik and Kok-Peng Ang, pp 452 DOI:10.1039/DT9810000452 |
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Matrix isolation studies on Cs2[CO3], Rb2[CO3], and K2[CO3]. The shape of molecular K2[CO3] J. Steven Ogden and Stephen J. Williams, pp 456 DOI:10.1039/DT9810000456 |
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Reactivity of tetra-n-butylammonium di-µ-chloro-bis[bis(pentafluorophenyl)palladate(II)]. A general method for the synthesis of cis isomers of neutral and anionic palladium(II) complexes Rafael Usón, Juan Forniés, Pablo Espinet, Francisco Martínez and Milagros Tomás, pp 463 DOI:10.1039/DT9810000463 |
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Electron spin resonance study of some copper(II) dithiocarbamates and their mixed-ligand complexes William J. Newton and Brian J. Tabner, pp 466 DOI:10.1039/DT9810000466 |
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The molecular structure of tetraborane(10) in the gas phase as determined by a joint analysis of electron-diffraction and microwave data C. John Dain, Anthony J. Downs, Graham S. Laurenson and David W. H. Rankin, pp 472 DOI:10.1039/DT9810000472 |
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Flash-photolysis studies of the electron-transfer reactions of dioxygen complexes of cobalt(III) with tris(2,2-bipyridyl)ruthenium(III) K. Chandrasekaran and P. Natarajan, pp 478 DOI:10.1039/DT9810000478 |
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Silver(I) complexes of the potentially chelating olefinic ligands 2,2-dimethylbut-3-enyl methyl sulphide and 2,2-dimethyl-2-silabut-3-enyl methyl sulphide. Crystal structure analysis of bis(2,2-dimethylbut-3-enyl methyl sulphide)silver(I) tetrafluoroborate, (2,2-dimethylbut-3-enyl methyl sulphide)silver(I) perchlorate, (2,2-dimethylbut-3-enyl methyl sulphide)nitratosilver(I), and (2,2-dimethylbut-3-enyl methyl sulphide)-trifluoroacetatosilver(I) Elmer C. Alyea, George Ferguson, Alan McAlees, Robert McCrindle, Ron Myers, Pik Y. Siew and Shelton A. Dias, pp 481 DOI:10.1039/DT9810000481 |
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A critical examination of the interaction between copper(II) and glycylglycyl-L-histidine Show-jy Lau and Bibudhendra Sarkar, pp 491 DOI:10.1039/DT9810000491 |
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Structural and mechanistic studies of co-ordination compounds. Part 26. Synthesis and characterization of some octahedral complexes of ruthenium-(II) and -(III) with macrocyclic quadridentate thioethers Chung-Kwong Poon and Chi-Ming Che, pp 495 DOI:10.1039/DT9810000495 |
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Complexation and solvent extraction of lithium salts with 2,3,6,7,9,10-hexahydro-5H-1,4,8,11-benzotetraoxacyclotridecin (benzo-13-crown-4) Uriel Olsher and Joseph Jagur-Grodzinski, pp 501 DOI:10.1039/DT9810000501 |
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The crystal structure of di-µ-ethanethiolato-µ-sulphido-bis[dichloro-(tetrahydrothiophen)tungsten(IV)(W-W)]: a confacial bioctahedral complex with a tungsten-to-tungsten bond P. Michael Boorman, K. Ann Kerr and Vikram D. Patel, pp 506 DOI:10.1039/DT9810000506 |
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Crystallographic studies of the boron-nitrogen bond in aminoboranes. Part 5. The crystal and molecular structure of 1,5,9-triaza-13-boratricyclotridecane Graham J. Bullen, pp 511 DOI:10.1039/DT9810000511 |
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Crystal and molecular structure of tetra-µ3-carbonyl-octacarbonyl-tetrakis(triphenyl phosphite)-octahedro-hexarhodium Gianfranco Ciani, Mario Manassero and Vincenzo G. Albano, pp 515 DOI:10.1039/DT9810000515 |
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High nuclearity carbonyl clusters of rhodium. Part 2. Crystal and molecular structure of the tetramethylammonium salt of dodeca-µ-carbonyl-dodecacarbonylhydrido-polyhedro-tridecarhodate(4-)-1-methylpyrrolidin-2-one (1/3) Gianfranco Ciani, Angelo Sironi and Secondo Martinengo, pp 519 DOI:10.1039/DT9810000519 |
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Electronic, infrared, and resonance-Raman spectra of mixed-valence iodide-bridged linear-chain complexes of platinum Robin J. H. Clark and Mohamedally Kurmoo, pp 524 DOI:10.1039/DT9810000524 |
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A carbon-13 nuclear magnetic resonance study of (arene)(cyclopentadienyl)iron salts Barry R. Steele, Ronald G. Sutherland and Choi Chuck Lee, pp 529 DOI:10.1039/DT9810000529 |
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New adducts of phthalocyaninatocobalt(II) with base molecules. Part 3. Chemical and spectroscopic relations between mono (low- and high-spin) and bis adducts Franco Cariati, Giovanni Micera, Maria Antonietta Zoroddu and Franca Morazzoni, pp 535 DOI:10.1039/DT9810000535 |
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Macro-inorganics. Part 6. Protonation and complex formation of a new series of polymers whose repeating units behave independently Paolo Ferruti, Nicola Danzo, Leone Oliva, Rolando Barbucci and Vincenzo Barone, pp 539 DOI:10.1039/DT9810000539 |
Studies of some ternary complexes of copper(II) involving  -bonding ligandsK. Gopalakrishnan and Pabitra K. Bhattacharya, pp 543 DOI:10.1039/DT9810000543 |
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Bonding in clusters. Part 2. Hexaborane(10) and related metalloboranes Paul Brint, W. Kevin Pelin and Trevor R. Spalding, pp 546 DOI:10.1039/DT9810000546 |
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Group 4 organometallic compounds. Part 8. Preparation and Mössbauer spectra of five- and six-co-ordinate di- and tri-organotin compounds containing mixed phenyl and butyl groups on tin V. G. Kumar Das, Ng Seik Weng, Peter J. Smith and Robin Hill, pp 552 DOI:10.1039/DT9810000552 |
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Studies of chelation. Part 9. Cobalt complexes of 1-[(substituted phenyl)azo]-2-naphthol and 1-[(substituted phenylimino)methyl]-2-naphthol ligands. Tautomerism and reactivity Joseph A. Connor, David J. Fine and Raymond Price, pp 559 DOI:10.1039/DT9810000559 |
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Crystal structure and electronic properties of bis (2,2-bipyridyl)formatocopper(II) tetrafluoroborate-water (2/1) William Fitzgerald and Brian J. Hathaway, pp 567 DOI:10.1039/DT9810000567 |
Transition metal-carbon bonds. Part 49. The action of amines on cis-[PtCl2(PPrn3)(C3H4)]: crystal structures of the complexes [PtCl(PPrn3){C( CH2)CH2NHBut}](four-membered ring) and [Pt2Cl2(PPrn3)2{C(CH2)CH2NHMe}2](eight-membered ring)John R. Briggs, Christopher Crocker, Walter S. McDonald and Bernard L. Shaw, pp 575 DOI:10.1039/DT9810000575 |
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Kinetics and mechanisms of redox reactions in aqueous solution. Part 6. Oxidation of cyclohexanone by aquamanganese(III) ions in aqueous perchloric acid Ratan Raj Nagori, Mahendra Mehta and Raj Narain Mehrotra, pp 581 DOI:10.1039/DT9810000581 |
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The rate and mechanism of tetracyanoethylene addition of cycloheptatriene and related complexes of tricarbonyliron Suman K. Chopra, Michael J. Hynes and Patrick McArdle, pp 586 DOI:10.1039/DT9810000586 |
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Electron spin resonance studies of axial ligation to cobalt (II)complexes. Part 2. Interaction with phosphorus ligands. Analysis of the cobalt bonding parameters and the phosphorus hyperfine coupling Gérard Labauze and J. Barrie Raynor, pp 590 DOI:10.1039/DT9810000590 |
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Conformational studies of the phosphazenyl side chain in cyclophosphazenes. Part 3. Crystal and molecular structure of N3P3Cl4(NEt2)(NPPh3) Y. Sudhakara Babu, Hattikudur Manohar and Robert A. Shaw, pp 599 DOI:10.1039/DT9810000599 |
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Electron spin resonance spectra and conformations of Group 2 ion complexes with a semidione ligand Marina Brustolon, Luigi Pasimeni and Carlo Corvaja, pp 604 DOI:10.1039/DT9810000604 |
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Model compounds for microbial iron-transport compounds. Part 1. Solution chemistry and Mössbauer study of iron(II) and iron(III) complexes from phenolic and catecholic systems Robert C. Hider, A. Rahim Mohd-Nor, Jack Silver, Ian E. G. Morrison and Lovat V. C. Rees, pp 609 DOI:10.1039/DT9810000609 |
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Bis(arylazo-oximato)palladium(II); synthesis, palladium-nitrogen bond lability, and redox activity Pinaki Bandyopadhyay, Pradip K. Mascharak and Animesh Chakravorty, pp 623 DOI:10.1039/DT9810000623 |
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Photochemical studies of the alkylammoniun molybdates. Part 5. Photolysis in weak acid solutions Toshihiro Yamase, Ryoichi Sasaki and Tsuneo Ikawa, pp 628 DOI:10.1039/DT9810000628 |
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Photochemical preparation of the cis isomers of dichlorobis(tri-n-alkyl-phosphine)palladium(II)(alkyl = Et, Prn, or Bun); the crystal-structure analysis of the overcrowded n-propyl homologue Nathaniel W. Alcock, Terence J. Kemp and Franz L. Wimmer, pp 635 DOI:10.1039/DT9810000635 |
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Tin-119 Fourier-transform nuclear magnetic resonance study of rhodium-tin complexes formed in aqueous hydrochloric acid solutions of RhCl3 and SnCl2 Hiroshi Moriyama, Toshiya Aoki, Sumio Shinoda and Yasukazu Saito, pp 639 DOI:10.1039/DT9810000639 |
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Heterogeneous equilibrium of calcium silicate hydrate in water at 30 °C Kinjiro Fujii and Wakichi Kondo, pp 645 DOI:10.1039/DT9810000645 |
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Notes. Crystal structure of tetrachlorobis[o-phenylenebis(dimethylarsine)]-niobium(IV) David L. Kepert, Brian W. Skelton and Allan H. White, pp 652 DOI:10.1039/DT9810000652 |
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Preparation of three- and four-co-ordinate gold(I) complexes; crystal structure of bis[o-phenylenebis(dimethylarsine)]gold(I) bis(pentafluorophenyl)aurate(I) Rafael Usón, Antonio Laguna, Jose Vicente, Javier Garcia, Peter G. Jones and George M. Sheldrick, pp 655 DOI:10.1039/DT9810000655 |
Ian J. Colquhoun and William McFarlane,
pp 658 DOI:10.1039/DT9810000658
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Back cover J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100BX007 |
Issue 3
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Front cover J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100FX009 |
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Contents pages J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100FP013 |
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Chemical synthesis with metal atoms. The preparation and structure of cyclo-octadiene trifluorophosphine complexes of chromium. The crystal structure of (5-cyclo-octa-1,3-dienyl)hydridotris(trifluorophosphine) chromium J. Richard Blackborow, Colin R. Eady, Friedrich-Wilhelm Grevels, (the late) Ernst A. Koerner von Gustorf, Alberto Scrivanti, Otto S. Wolfbeis, Reinhard Benn, David J. Brauer, Carl Krüger, Paul J. Roberts and Yi-Hung Tsay, pp 661 DOI:10.1039/DT9810000661 |
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Topochemically controlled hydrogen reduction of scheelite-related rare-earth metal molybdates Jagannatha Gopalakrishnan and Arumugam Manthiram, pp 668 DOI:10.1039/DT9810000668 |
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Metal carbonyl photochemistry. Part 3. Behaviour of [Mn(-C5H5)-(CO)3] and related species at 77 K John David Black, Michael J. Boylan and Paul S. Braterman, pp 673 DOI:10.1039/DT9810000673 |
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Nuclear magnetic shift and relaxation effects resulting from complexation of lanthanide ions with endo-cis-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Muriel Delepierre, Christopher M. Dobson and Stephen L. Menear, pp 678 DOI:10.1039/DT9810000678 |
Copper(II) complexes of N,N-bis( -carbamoylethyl)trimethylenediamine in aqueous solutionMin-Shiun Chao and Chung-Sun Chung, pp 683 DOI:10.1039/DT9810000683 |
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Analysis of the luminescence spectra of some uranates Denise M. Krol, pp 687 DOI:10.1039/DT9810000687 |
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Square planar co-ordination of the 12-membered macrocyclic tetraamine ligand 1,4,7,10-tetra-azacyclododecane-2,6-dione Mutsuo Kodama and Eiichi Kimura, pp 694 DOI:10.1039/DT9810000694 |
Carbene complexes. Part 17. Crystal structure of trans-tetracarbonylbis(1,3-dimethylimidazolidin-2-ylidene)molybdenum(0), trans-[Mo(CO)4{CN(Me)CH2CH2NMe}2], structural comparison with the cis isomer, and a kinetic study of the trans cis isomerisationMichael F. Lappert, Peter L. Pye, Anthony J. Rogers and George M. McLaughlin, pp 701 DOI:10.1039/DT9810000701 |
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The interaction of hydrogen with tri-µ-chloro-hexakis(trimethylsilylmethyl)-triangulo-trirhenium(III), its adducts with carbon monoxide, triphenylphosphine, and pyridine and with tri-µ-chloro-chloropentakis-(trimethylsilylmethyl)-triangulo-trirhenium(III). The X-ray crystal structures of hydridononakis(trimethylsilylmethyl)bis[tri-µ-chloro-triangulo-trirhenium(III)], tri-µ-chloro-chlorohydridotetrakis(trimethyl-silylmethyl)(triphenylphosphine)-triangulo-trirhenium(III), and syn,syn,-anti-trichloro-tris(µ-trimethylsilylmethyl)-tris(trimethylsilylmethyl)-triangulo-trirhenium(III) Konstantinos Mertis, Peter G. Edwards, Geoffrey Wilkinson, K. M. Abdul Malik and Michael B. Hursthouse, pp 705 DOI:10.1039/DT9810000705 |
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New carbide clusters in the cobalt sub-group. Part 7. Preparation and structural characterization of carbido-hexa-µ-carbonyl-heptacarbonyl-polyhedro-hexarhodate(2-) as its bis(tetraphenylphosphonium) salt Vincenzo G. Albano, Dario Braga and Secondo Martinengo, pp 717 DOI:10.1039/DT9810000717 |
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Kinetics and mechanisms of reduction of a nickel(IV) complex by ascorbate ion A. Graham Lappin, Mauro C. M. Laranjeira and Lawson Youde-Owei, pp 721 DOI:10.1039/DT9810000721 |
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Thermochemistry of hexafluoro-anions of MIV(M = Si, Ti, Mn, or Re) and lattice energy calculations for their salts Michael J. Blandamer, John Burgess, Stephen J. Hamshere, Raymond D. Peacock, John H. Rogers and H. Donald B. Jenkins, pp 726 DOI:10.1039/DT9810000726 |
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Spin density and cobalt electronic structure in phthalocyaninatocobalt(II): a polarised neutron diffraction study Geoffrey A. Williams, Brian N. Figgis and Ronald Mason, pp 734 DOI:10.1039/DT9810000734 |
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Chemistry of di- and tri-metal complexes with bridging carbene or carbyne ligands. Part 6. Synthesis of platinum-chromium and -tungsten compounds. X-Ray crystal structure of [(Me3P)(OC)4W{µ-C(OMe)C6H4Me-4}Pt(PMe3)2] Judith A. K. Howard, Kevin A. Mead, John R. Moss, Rafael Navarro, F. Gordon A. Stone and Peter Woodward, pp 743 DOI:10.1039/DT9810000743 |
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Chemistry of di- and tri-metal complexes with bridging carbene or carbyne ligands. Part 7. Interconversion of carbene and carbyne ligands at a dimetal centre. X-Ray crystal structures of [CrPt{µ-C(CO2Me)Ph}(CO)4(PMe3)3] and [ MnPt(µ-CC6H4Me-4)(CO)2(PMe3)2(-C5H5)][BF4]·CH2Cl2 Judith A. K. Howard, John C. Jeffery, Mariano Laguna, Rafael Navarro and F. Gordon A. Stone, pp 751 DOI:10.1039/DT9810000751 |
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Chemistry of di- and tri-metal complexes with bridging carbene or carbyne ligands. Part 8. Synthesis of the trimetal compounds [M{W(µ-CC6H4Me-4)(CO)2(-C5H5)}2](M = Ni, Pd, or Pt) and crystal structures of the platinum and nickel complexes T. V. Ashworth, Michael J. Chetcuti, Judith A. K. Howard, F. Gordon A. Stone, Simon J. Wisbey and Peter Woodward, pp 763 DOI:10.1039/DT9810000763 |
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Dirhenium complexes containing two, three, and four linked acetylene molecules derived from the reaction of [Re2(CO)10] with RC2R (R = Ph or Me); the X-ray crystal structure of [Re2(CO)4{(PhCCPh)3}(CNCH2SO2C6H4Me-p)2]· CH2Cl2 Martin J. Mays, David W. Prest and Paul R. Raithby, pp 771 DOI:10.1039/DT9810000771 |
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Synthesis and properties of dialkyl complexes of nickel(II). The crystal structure of bis(pyridine)bis(trimethylsilylmethyl)nickel(II) Ernesto Carmona, Francisco González, Manuel L. Poveda, Jerry L. Atwood and Robin D. Rogers, pp 777 DOI:10.1039/DT9810000777 |
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The potassium fluoride-boric acid system. Hydrogen bonding in KF·H3BO3 John Emsley, Victor Gold, Jeremy Lucas and Richard E. Overill, pp 783 DOI:10.1039/DT9810000783 |
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Combined X-ray and neutron diffraction study of [Os4(CO)11H3(CHCHPh)] Brian F. G. Johnson, Jack Lewis, A. Guy Orpen, Paul R. Raithby and Keith D. Rouse, pp 788 DOI:10.1039/DT9810000788 |
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Carbonyl complexes of niobium and tantalum and evidence of a niobium dinitrogen complex: the structure of carbonyldichlorocyclopentadienylbis(dimethylphenylphosphine)tantalum Roger J. Burt, G. Jeffery Leigh and David L. Hughes, pp 793 DOI:10.1039/DT9810000793 |
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Redox-potential-structure relationships in metal complexes. Part 4. Electron-poor dinitrogen complexes of rhenium(I) G. Jeffery Leigh, Robert H. Morris, Christopher J. Pickett, David R. Stanley and Joseph Chatt, pp 800 DOI:10.1039/DT9810000800 |
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Metallocene derivatives of early transition metals. Part 2. Substituted cyclopentadienyl Group 4A dichloro-metallocene complexes [M(-C5H4R)2Cl2](M = Zr or Hf; R = Me, Et, Pri, But, or SiMe3), their mono- and di-alkyl derivatives [M(-C5H4R)2RX](X = Cl or R; R= CH2SiMe3 or CH2CMe3), and their d1 reduction products Michael F. Lappert, Christopher J. Pickett, Paul I. Riley and Paul I. W. Yarrow, pp 805 DOI:10.1039/DT9810000805 |
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Metallocene derivatives of early transition elements. Part 3. Synthesis, characterisation, conformation, and rotational barriers [for the Zr-C(sp3) bond] of the zirconium(IV) complexes [Zr(-C5H4R)2{CH-(SiMe3)2}Cl] and the crystal and molecular structures of the t-butyl and trimethylsilyl complexes (R = CMe3 or SiMe3) Michael F. Lappert, Paul I. Riley, Paul I. W. Yarrow, Jerry L. Atwood, William E. Hunter and Michael J. Zaworotko, pp 814 DOI:10.1039/DT9810000814 |
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Electron spin resonance study of copper(II)-amino-acid complexes: evidence for cis and trans isomers and the structures of copper(II)-histidinate complexes in aqueous solution Bernard A. Goodman, Donald B. McPhail and H. Kipton J. Powell, pp 822 DOI:10.1039/DT9810000822 |
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Synthesis and reactivity of trinuclear osmium and dinuclear and trinuclear ruthenium compounds derived from hydroxyalkynes Silvio Aime and Antony J. Deeming, pp 828 DOI:10.1039/DT9810000828 |
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The light-induced blackening of red mercury(II) sulphide R. Stephen Davidson and Charles J. Willsher, pp 833 DOI:10.1039/DT9810000833 |
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Reactions of silanes and germanes with iridium complexes. Part 3. Reactions of some silyl derivatives of O, S, Se, N, and P with trans-carbonyliodobis(triethylphosphine)iridium(I) E. A. V. Ebsworth, Hugh M. Ferrier and Thomas E. Fraser, pp 836 DOI:10.1039/DT9810000836 |
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Some binuclear complexes of platinum containing single PF2 bridges E. A. V. Ebsworth, David W. H. Rankin and John D. Whitelock, pp 840 DOI:10.1039/DT9810000840 |
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Isomerism in adducts of tin(IV) tetrahalides with NN-dimethylacetamide, NN-dimethylformamide, and dimethyl sulphoxide in the solid state Celso U. Davanzo and Yoshitaka Gushikem, pp 843 DOI:10.1039/DT9810000843 |
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Mono--cyclopentadienylmolybdenum chemistry. Some oxo-, oxohalogeno-, halogeno-, thio-, -disulphido-, and thiohalogeno-derivatives Mark J. Bunker and Malcolm L. H. Green, pp 847 DOI:10.1039/DT9810000847 |
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Synthesis and crystal and molecular structure of di-µ-(N-methylpiperidinium-4-thiolate)-bis[dichlorozinc(II)] monohydrate Marie C. Briansó, José L. Briansó, Walter Gaete, Josep Ros and Carmen Suñer, pp 852 DOI:10.1039/DT9810000852 |
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Transition-metal complexes of pyrrole pigments. Part 20. Redox behaviour of chromium complexes with macrocyclic tetrapyrroles Yukito Murakami, Yoshihisa Matsuda and Sunao Yamada, pp 855 DOI:10.1039/DT9810000855 |
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Alkyne complexes of platinum. Part 5. Di- and tri-platinum complexes with bridging trimethylsilyl-substituted alkyne ligands; crystal structure of [Pt2(µ-PhC2SiMe3)(C8H12)2] Neil M. Boag, Michael Green, Judith A. K. Howard, F. Gordon A. Stone and Hubert Wadepohl, pp 862 DOI:10.1039/DT9810000862 |
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Reactions of co-ordinated ligands. Part 24. The reaction of bis-(but-2-yne)carbonyl(-cyclopentadienyl or 5-indenyl)molybdenum tetrafluoroborate with acetonitrile and phosphines; crystal structures of but-2-ynecarbonyl(5-indenyl)(triethylphosphine)molybdenum tetrafluoroborate and but-2-yne(5-indenyl)bis(trimethylphosphine)molybdenum tetrafluoroborate Stephen R. Allen, Paul K. Baker, Stephen G. Barnes, Michael Green, Lynda Trollope, Ljubica Manojlovi  -Muir and Kenneth W. Muir,pp 873 DOI:10.1039/DT9810000873 |
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Diene-metal bonding. Some unexpected effects of Group 5 donor ligands on carbon-13 nuclear magnetic resonance parameters and X-ray crystal structures Anthony J. Pearson and Paul R. Raithby, pp 884 DOI:10.1039/DT9810000884 |
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Notes. Open-shell molybdenum carbonyl complexes and the binding of -acid ligands to higher-oxidation-state molybdenum sites Brian A. L. Crichton, Jon R. Dilworth, Christopher J. Pickett and Joseph Chatt, pp 892 DOI:10.1039/DT9810000892 |
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Kinetics of the reduction of (ethylenediaminetetra-acetato)cobaltate(III) and related complexes by chromium(II) ions Hiroshi Ogino, Etsuko Kikkawa, Makoto Shimura and Nobuyuki Tanaka, pp 894 DOI:10.1039/DT9810000894 |
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Back cover J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100BX011 |
Issue 4
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Front cover J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100FX013 |
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Contents pages J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100FP017 |
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Kinetics and mechanisms of redox reactions in aqueous solution. Part 7. Decarboxylation of aliphatic acids by aquasilver (II) ions Raj Narain Mehrotra, pp 897 DOI:10.1039/DT9810000897 |
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Dioxomolybdenum(VI) complexes of quadridentate chiral Schiff bases and the crystal and molecular structure of dioxo[(2R)-propane-1,2-diylbis(salicylideneiminato)]molybdenum(VI) Michele Gullotti, Alessandro Pasini, Gian Maria Zanderighi, Gianfranco Ciani and Angelo Sironi, pp 902 DOI:10.1039/DT9810000902 |
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Low-frequency vibrational spectra of some 4-benzylpiperidinium and N-benzylpiperazinium pentahalogenoantimonates(III) and pentahalogenobismuthates(III). Partial crystal structure determination of 4-benzylpiperidinium pentachloroantimonate(III) Franco Cariati, Angelo Panzanelli, Luciano Antolini, Ledi Menabue, Gian Carlo Pellacani and Giuseppe Marcotrigiano, pp 909 DOI:10.1039/DT9810000909 |
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Spectroscopy of cobalt-ethylenediamine-oxygen adducts in the supercages of zeolites Robert A. Schoonheydt and Jozefien Pelgrims, pp 914 DOI:10.1039/DT9810000914 |
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Mechanisms of organometallic substitution reactions. Part 4. Kinetics of replacement of dimethyl sulphoxide (dmso) from [RuX2(-C6H6)(dmso)](X = Cl or Br) complexes by triphenylphosphine Christopher M. Carr, Daphne M. Davies, Marian Gower, Leon A. P. Kane-Maguire and Dwight A. Sweigart, pp 923 DOI:10.1039/DT9810000923 |
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Co-ordination compounds of indium. Part 38. Complexes of indium(I) and indium(III) with macrocyclic ligands Michael J. Taylor, Dennis G. Tuck and Luis Victoriano, pp 928 DOI:10.1039/DT9810000928 |
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Synthesis of platinum(II) alkyl and aryl complexes from K2[PtCl4] and tetraorganotin compounds in dimethyl sulphoxide Colin Eaborn, Kalipada Kundu and Alan Pidcock, pp 933 DOI:10.1039/DT9810000933 |
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Resonance-Raman and infrared studies of cyanide-bridged dimetal complexes Ronald E. Hester and El Metwally Nour, pp 939 DOI:10.1039/DT9810000939 |
Three-, four-, and five-co-ordination modes of a potentially quinquedentate  nitrogen-sulphur macrocyclic ligand: the crystal and molecular structures of two copper(II) complexesMichael G. B. Drew, Colin Cairns, S. Martin Nelson and Jane Nelson, pp 942 DOI:10.1039/DT9810000942 |
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Influence of fluorine substitution on the proton conductivity of hydroxyapatite Gobinda C. Maiti and Friedemann Freund, pp 949 DOI:10.1039/DT9810000949 |
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Chemistry of the Group 1B metals. Part 15. Some diphenylbis(pyrazolyl)borate complexes of silver, and the crystal and molecular structures of [Ag{P(C6H4Me-p)3}{BPh2(pz)2}](pz = pyrazolyl) Michael I. Bruce, John D. Walsh, Brian W. Skelton and Allan H. White, pp 956 DOI:10.1039/DT9810000956 |
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Chemistry of the Group 1B metals. Part 16. Crystal and molecular structures of [ortho-phenylenebis(dimethylarsine)][tetrakis(1-pyrazolyl)borato-N2,N2]copper(I) and bis[ortho-phenylenebis(dimethylarsine)]-copper(I) hexafluorophosphate(V) Omar M. Abu Salah, Michael I. Bruce, Philippa J. Lohmeyer, Colin L. Raston, Brian W. Skelton and Allan H. White, pp 962 DOI:10.1039/DT9810000962 |
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Spectrochemistry of solutions. Part 12. Cyano-complexes of silver(I) in solution in liquid ammonia Peter Gans, J. Bernard Gill, Mervyn Griffin and Peter C. Cahill, pp 968 DOI:10.1039/DT9810000968 |
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The d-electron optical activity of tetrahedral dichloro[(-)-spartein]-cobalt(II) Alex F. Drake, Reiko Kuroda, Stephen F. Mason, Robert D. Peacock and Brian Stewart, pp 976 DOI:10.1039/DT9810000976 |
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The aquation of trans-bis(ethylenediamine)difluorochromium(III) and related lons in aqueous solutions of strong acids Mahmoud Delavar and Peter J. Staples, pp 981 DOI:10.1039/DT9810000981 |
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Preparation and crystal structure analysis of a vinyl ether chelate, dichloro[4-methoxy-2,2,N,N-tetramethylbut-(Z)-3-enylamine]palladium(II), and its conversion into di-µ-chloro-bis[3-(dimethylamino)-1-formyl-2,2-dimethylpropyl-C,N]dipalladium(II) Robert McCrindle, George Ferguson, Masood A. Khan, Alan J. McAlees and Barbara L. Ruhl, pp 986 DOI:10.1039/DT9810000986 |
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Binary and ternary complexes of copper(II) containing some potentially tridentate ligands Madhavan Sivasankaran Nair and Muchi Santappa, pp 992 DOI:10.1039/DT9810000992 |
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The magnetic, spectral, and structural properties of trans-tetra-amminedinitronickel(II) Brian N. Figgis, Philip A. Reynolds, Allan H. White, Geoffrey A. Williams and Steven Wright, pp 997 DOI:10.1039/DT9810000997 |
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Studies on organometallic hetero-multiple-bridged molecules. Part 7. Synthesis and properties of dichalcogenide-bridged complexes of rhenium(I) and the crystal and molecular structures of the diphenyl ditelluride-bridged complex, [Re2Br2(CO)6(Te2Ph2)] Fausto Calderazzo, Dario Vitali, Rinaldo Poli, Jerry L. Atwood, Robin D. Rogers, James M. Cummings and Ivan Bernal, pp 1004 DOI:10.1039/DT9810001004 |
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Reactions of silanes and germanes with iridium complexes. Part 4. Reactions with carbonylhydridotris(triphenylphosphine)iridium(I) E. A. V. Ebsworth, Thomas E. Fraser, Steven G. Henderson, Diana M. Leitch and David W. H. Rankin, pp 1010 DOI:10.1039/DT9810001010 |
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Structural and mechanistic studies of co-ordination compounds. Part 28. Some octahedral ruthenium complexes of 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetra-azacyclotetradeca-1,3,8,10-tetraene produced by oxidative dehydrogenation reactions Chung-Kwong Poon and Chi-Ming Che, pp 1019 DOI:10.1039/DT9810001019 |
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Crystal structure and spectroscopic properties of mercury(II) halide complexes. Part 3. The di-n-butyl sulphoxide-mercury(II) chloride (1/1) adduct Paolo Biscarini, Luciano Fusina, Giandomenico Nivellini and Giancarlo Pelizzi, pp 1024 DOI:10.1039/DT9810001024 |
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Preparation, structures, and reactions of some difluorothiophosphonate and difluoroselenophosphonate complexes of platinum(II) J. Andrew S. Duncan, E. A. V. Ebsworth, Robert O. Gould, C. Lynn Jones, David W. H. Rankin and John D. Whitelock, pp 1028 DOI:10.1039/DT9810001028 |
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Transition metal-diene complexes. Part 4. The crystal and molecular structure and isomerization of -cyclopentadienyl(-3-methoxycarbonylcyclohexa-1,4-diene)rhodium(I) Michael G. B. Drew, Catrionia M. Regan and S. Martin Nelson, pp 1034 DOI:10.1039/DT9810001034 |
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Derivatives of the energy levels of a molecular system with respect to parameters of the Hamiltonian, and their application to magnetic susceptibility calculations and least-squares fitting Antony B. Blake, pp 1041 DOI:10.1039/DT9810001041 |
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Molecular structure of bis(difluorophosphino)germylamine in the gas phase, determined by electron diffraction Graham S. Laurenson and David W. H. Rankin, pp 1047 DOI:10.1039/DT9810001047 |
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Synthesis and crystal structure of the trimetal compound [Pt3(C2H4)(C8H8)2(1,5-C8H12)2]: a complex of platinum(0) and platinum(II) Neil M. Boag, Judith A. K. Howard, John L. Spencer and F. Gordon A. Stone, pp 1051 DOI:10.1039/DT9810001051 |
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Preparation and spectra of a series of tautomeric compounds, [NiCo(-dienyl)(CO)4L](dienyl = C5H5 or C5H4Me; L = tertiary phosphine or arsine) A. R. Manning, pp 1057 DOI:10.1039/DT9810001057 |
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Notes. A spectroscopic and crystallographic study of the [ReNCl4]- ion Werner Liese, Kurt Dehnicke, Robin D. Rogers, Riz Shakir and Jerry L. Atwood, pp 1061 DOI:10.1039/DT9810001061 |
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Kinetics and mechanisms of dissociation of metal chelates. Part 3. Effects of ions on the acid hydrolysis of tris(1,10-phenanthroline)iron(II) perchlorate Matthieu Tubino and Eduardo J. S. Vichi, pp 1064 DOI:10.1039/DT9810001064 |
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Crystal structure and absolute configuration of an isomer of potassium carbonatobis(L-valinato)cobaltate(III) dihydrate Michael G. Price and David R. Russell, pp 1067 DOI:10.1039/DT9810001067 |
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Back cover J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100BX015 |
Issue 5
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Front cover J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100FX017 |
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Contents pages J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100FP021 |
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Spin-spin interactions in polynuclear nickel(II) complexes: a susceptibility and low-temperature magnetisation study of the linear trimer hexakis(allylamine)hexakis-µ-benzotriazolyl-trinickel(II)-triphenylphosphine oxide (1/2) Peter D. W. Boyd and Raymond L. Martin, pp 1069 DOI:10.1039/DT9810001069 |
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Coupling of organic halides electrocatalyzed by the NiII/NiI/Ni0-PPh3 system. A mechanistic study based on an electroanalytical approach Gilberto Schiavon, Gino Bontempelli and Benedetto Corain, pp 1074 DOI:10.1039/DT9810001074 |
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Platinum-195 nuclear magnetic resonance study of platinum(0) complexes containing a series of acetylenes Yasuyuki Koie, Sumio Shinoda and Yasukazu Saito, pp 1082 DOI:10.1039/DT9810001082 |
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Stereoselectivity in the cross-metathesis of oct-1-ene and cis- or trans-oct-2-ene Akira Uchida, Masayoshi Hinenoya and Toshihiko Yamamoto, pp 1089 DOI:10.1039/DT9810001089 |
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Kinetics and mechanism of the reaction between tetrachloro- and tetrabromo-aurate(III) and thiocyanate Lars I. Elding, Ann-B. Gröning and Östen Gröning, pp 1093 DOI:10.1039/DT9810001093 |
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Tris(trimethylsilyl)methyltin oxinates and their conversion into bis-(trimethylsilyl)methyltin oxinates Frank Glockling and Wee Kong Ng, pp 1101 DOI:10.1039/DT9810001101 |
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Vanadium-51 and oxygen-17 nuclear magnetic resonance study of vanadate(V) equilibria and kinetics Elizabeth Heath and Oliver W. Howarth, pp 1105 DOI:10.1039/DT9810001105 |
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Reaction of bicyclo [n.1.0]alkanes (n= 3-6) with the olefin-metathesis catalysts tungsten hexachloride-tetraphenyltin and tungsten hexachloride-ethylaluminium dichloride Akira Uchida and Kazuyuki Hata, pp 1111 DOI:10.1039/DT9810001111 |
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Equilibrium and kinetic parameters of the oxygenation reaction of oxygen carriers. Conformational effects in cobalt(II) Schiff-base chelates derived from salicylaldehyde and substituted ethylenediamines Anna Puxeddu and Giacomo Costa, pp 1115 DOI:10.1039/DT9810001115 |
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Equilibrium and kinetic study of the reaction between phthalocyaninatoiron(II) and carbon monoxide in dimethyl sulphoxide Claudio Ercolani, Fabrizio Monacelli, Giovanna Pennesi, Gentilina Rossi, Eraldo Antonini, Paolo Ascenzi and Maurizio Brunori, pp 1120 DOI:10.1039/DT9810001120 |
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Characterization of metal-to-ligand charge-transfer and intraligand transitions of fac-[Re(CO)3L(X)] complexes [L = di-imine; X = halide or Mn(CO)5] and explanation of the photochemistry of [Re(CO)3L{Mn(CO)5}] using the resonance Raman effect Roelof W. Balk, Derk J. Stufkens and Ad Oskam, pp 1124 DOI:10.1039/DT9810001124 |
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Chemistry of the metal carbonyls. Part 79. Synthesis and X-ray crystal structures of [N(PPh3)2][Fe2Pt2(µ-H)(µ-CO)3(CO)5(PPh3)2], [Fe2Pt2(µ-H)2(CO)8(PPh3)2], and [Fe2Pt(CO)8(cyclo-C8H12)] Louis J. Farrugia, Judith A. K. Howard, Pachanee Mitrprachachon, F. Gordon A. Stone and Peter Woodward, pp 1134 DOI:10.1039/DT9810001134 |
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Synthesis and vibrational spectroscopic study of compounds containing the I(SCN)2-, I2(SCN)-, and I(SeCN)2- ions Graham A. Bowmaker and David A. Rogers, pp 1146 DOI:10.1039/DT9810001146 |
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Strong hydrogen bonding in aliphatic diol solutions of alkali-metal fluorides James H. Clark, Raveendran K. Kanippayoor and Jack M. Miller, pp 1152 DOI:10.1039/DT9810001152 |
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Use of alkali- and alkaline-earth-metal ions in the template synthesis of 12-crown-4, 15-crown-5, and 18-crown-6 Brian R. Bowsher and Antony J. Rest, pp 1157 DOI:10.1039/DT9810001157 |
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Kinetics of nucleophilic attack on co-ordinated organic moieties. Part 17. Addition of pyridines to [Fe(1-5--dienyl)(CO)3]+ cations (dienyl = C6H7, 2-MeOC6H6, or C7H9) Timothy I. Odiaka and Leon A. P. Kane-Maguire, pp 1162 DOI:10.1039/DT9810001162 |
Cyclopentadienyl-ruthenium and -osmium chemistry. Part 14. The reaction between chloro(cyclopentadienyl)bis(triphenylphosphine)-ruthenium and trifluoroacetonitrile: crystal structure of [RuNH C(CF3)NC(CF3)NH{P(OMe)3}(-C5H5)]Valerie Robinson, Graham E. Taylor, Peter Woodward, Michael I. Bruce and Robert C. Wallis, pp 1169 DOI:10.1039/DT9810001169 |
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Enthalpies of formation of [M(-C5H5)2(OOCR)2] complexes; M = Mo, W, or Ti and R = C6H5 or CF3 Jorge C. G. Calado, Alberto R. Dias, Margarida S. Salema and José A. Martinho Simões, pp 1174 DOI:10.1039/DT9810001174 |
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Enthalpies of formation of [Mo(-C5H5)2(SR)2] complexes; R = n-C3H7, i-C3H7, n-C4H9, or t-C4H9 Alberto R. Dias, José A. Martinho Simões and Clementina Teixeira, pp 1178 DOI:10.1039/DT9810001178 |
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The electronic states of the tetrahedral iron clusters of iron-sulphur proteins. A theoretical model Andrew J. Thomson, pp 1180 DOI:10.1039/DT9810001180 |
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Preparation, characterization, and properties of 1,1-azo-o-carbaboranes Katsutoshi Aono and Tetsushi Totani, pp 1190 DOI:10.1039/DT9810001190 |
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Preparation and properties of alkyl- and aryl-substituted closo-closo- and closo-nido-hydrazocarbaboranes Katsutoshi Aono and Tetsushi Totani, pp 1196 DOI:10.1039/DT9810001196 |
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Reactions of hexamethyltungsten(VI) in the presence of trimethylphosphine. Synthesis of methyl, ethylidyne, hydrido-, alkoxo-, and other tungsten compounds. X-Ray crystal structures of trans-ethylidyne(methyl)tetrakis(trimethylphosphine)tungsten(IV) and trihydrido(phenoxo)tetrakis(trimethylphosphine)tungsten(IV) Kwok W. Chiu, Richard A. Jones, Geoffrey Wilkinson, Anita M. R. Galas, Michael B. Hursthouse and K. M. Abdul Malik, pp 1204 DOI:10.1039/DT9810001204 |
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Transition-metal tetrafluoride oxide-antimony pentafluoride adducts; preparation and characterization of the adducts MF4O·SbF5(M = Mo, W, or Re) and crystal structures of MoF4O·SbF5 and ReF4O·SbF5 John Fawcett, John H. Holloway and David R. Russell, pp 1212 DOI:10.1039/DT9810001212 |
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Strong hydrogen bonding in the polyfluorides: ab initio calculations and a new method of preparing potassium hydrogendifluoride James H. Clark, John Emsley, Deborah J. Jones and Richard E. Overill, pp 1219 DOI:10.1039/DT9810001219 |
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Oxidative-addition and reductive-elimination reactions involving platinum complexes and tetraorganotin compounds Colin Eaborn, Kalipada Kundu and Alan Pidcock, pp 1223 DOI:10.1039/DT9810001223 |
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Notes. Hydrolysis of hexa-aqua-aluminium(III) in organic media J. W. Akitt and Alan Farthing, pp 1233 DOI:10.1039/DT9810001233 |
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Bis(3-cyanopentane-2,4-dionato)dihalogenotin(IV) complexes Frank S. Delk and David W. Thompson, pp 1235 DOI:10.1039/DT9810001235 |
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An electronegativity scale based upon geometry changes on ionization Peter H. Blustin and William T. Raynes, pp 1237 DOI:10.1039/DT9810001237 |
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Resonance-Raman studies of the nitride-bridged complex K3[Ru2NCl8(OH2)2] Jeremy R. Campbell and Robin J. H. Clark, pp 1239 DOI:10.1039/DT9810001239 |
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Back cover J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100BX019 |
Issue 6
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Front cover J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100FX021 |
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Contents pages J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100FP025 |
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The stereochemistry of oxovanadium(IV) complexes derived from salicylaldehyde and polymethylenediamines Gabriel A. Kolawole and Kantilal S. Patel, pp 1241 DOI:10.1039/DT9810001241 |
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A procedure for the calculation of enthalpy changes from continuoustitration calorimetric experiments Alberto Vacca, Antonio Sabatini and Lucia Bologni, pp 1246 DOI:10.1039/DT9810001246 |
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Spectroscopic study of the structures of [M2(-C5H5)2(CO)n(CNR)4 -n] complexes (n= 1 or 2; M = Fe or Ru) in solution. The structure of cis-[(-C5H5)(OC)Fe(µ-CO)(µ-CNPri)Fe(CNPri)(-C5H5)] in the solid state Mary Ennis, Rajesh Kumar, Anthony R. Manning, James A. S. Howell, Pradeep Mathur, Anthony J. Rowan and Frederic S. Stephens, pp 1251 DOI:10.1039/DT9810001251 |
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Trimethylsilylation of zeolites. Evidence for the presence of adjacent aluminium atoms Neil H. Ray, Richard J. Plaisted and Steven Johnson, pp 1260 DOI:10.1039/DT9810001260 |
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Complexation and exchange reactions of some dimethylamino-substituted group 4 compounds Steven R. Wade and Gerald R. Willey, pp 1264 DOI:10.1039/DT9810001264 |
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Crystal structures of dextrorotatory and racemic sodium ammonium tartrate Reiko Kuroda and Stephen F. Mason, pp 1268 DOI:10.1039/DT9810001268 |
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Chemistry of the metal carbonyls. Part 80. Diosmiumdiplatinum carbonyl complexes derived from tetracarbonyldihydrido-osmium. X-Ray crystal structure of [Os2Pt2(µ-H)2(CO)8(PPh3)2] Louis J. Farrugia, Judith A. K. Howard, Pachanee Mitroprachachon, F. Gordon A. Stone and Peter Woodward, pp 1274 DOI:10.1039/DT9810001274 |
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Carbon-13 nuclear magnetic resonance study of dinuclear iron carbonyl xanthate complexes: dynamic behaviour and local scrambling of the carbonyls at one iron atom Henri Patin, Gérard Mignani, Alain Benoit and Michael J. McGlinchey, pp 1278 DOI:10.1039/DT9810001278 |
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Studies in cyclophosphazenes. Part 10. The mechanism for trans-isomer preference in the non-geminal diamination of hexachlorocyclotriphosphazene Jacob M. E. Goldschmidt and Rebecca Goldstein, pp 1283 DOI:10.1039/DT9810001283 |
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Water-ammonia exchange at amminerhodium(III) complexes in aqueous ammoniacal solution Sijbe Balt and Andries Jelsma, pp 1289 DOI:10.1039/DT9810001289 |
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Low-temperature magnetochemical and spectroscopic studies of variable-spin tris(monothiocarbamato)iron(III) and tris(diselenocarbamato)iron(III) complexes Dale L. Perry, Lon J. Wilson, Kenneth R. Kunze, Luke Maleki, Paola Deplano and Emanuele F. Trogu, pp 1294 DOI:10.1039/DT9810001294 |
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Solid-state reaction between strontium carbonate and silica Osamu Yamaguchi, Kazuhide Yabuno, Shigeru Yamamoto and Kiyoshi Shimizu, pp 1300 DOI:10.1039/DT9810001300 |
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Preparation, properties, and crystal and molecular structures of the cyanomethane adducts of niobium(IV) chloride and di-µ-sulphido-bis[dichloroniobium(IV)] A. John Benton, Michael G. B. Drew, Richard J. Hobson and David A. Rice, pp 1304 DOI:10.1039/DT9810001304 |
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Cyclopropenyl and oxocyclobutenyl complexes of molybdenum. Crystal and molecular structures of (2,2-bipyridine)bromodicarbonyl(1-3--1,2,3-triphenylcyclopropenyl)molybdenum(II) and (2,2-bipyridine)bromodicarbonyl(2-4--1-oxo-2,3,4-triphenylcyclobutenyl)molybdenum(II) Michael G. B. Drew, Brian J. Brisdon and Alan Day, pp 1310 DOI:10.1039/DT9810001310 |
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Reduction-oxidation properties of organotransition-metal complexes. Part 12. Formation of carbon-carbon bonds via the oxidative dimerisation of [Fe(CO)3(4-C8H8)] and the reduction of [Fe2(CO)6(5:5-C16H16)]2+; X-ray crystal structures of [Fe2(CO)4{P(OPh)3}2(5:5-C16H16)][PF6]2 and [Fe(CO)3(4-C16H16)] Neil G. Connelly, Raymond L. Kelly, Maureen D. Kitchen, Rona M. Mills, Robert F. D. Stansfield, Mark W. Whiteley, Susan M. Whiting and Peter Woodward, pp 1317 DOI:10.1039/DT9810001317 |
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Reactions of di-isopropylcarbodi-imide with some ruthenium and osmium hydrides, leading to ready dehydrogenation of an isopropyl group; crystal and molecular structure of carbonylchloro(N-isopropenyl-N-isopropylformamidinato)bis(triphenylphosphine)ruthenium(II) Arlo D. Harris, Stephen D. Robinson, Arvind Sahajpal and Michael B. Hursthouse, pp 1327 DOI:10.1039/DT9810001327 |
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Potentiometric and spectrophotometric study of the co-ordination compounds formed between copper(II) and dipeptides containing tyrosine Robert J. W. Hefford and Leslie D. Pettit, pp 1331 DOI:10.1039/DT9810001331 |
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Structural and mechanistic studies of co-ordination compounds. Part 29. Synthesis and characterization of some cis-macrocyclic secondary amine complexes of ruthenium Chung-Kwong Poon and Chi-Ming Che, pp 1336 DOI:10.1039/DT9810001336 |
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Co-ordination chemistry of sulphines. Part 4. Influence of the phosphine cone angle on both the oxidative addition of carbon-sulphur and carbon-chlorine side bonds in [Pt0(PR3)2(XYCSO)] complexes and the (E)-(Z) isomerization Johan W. Gosselink, Huibert Bulthuis and Gerard van Koten, pp 1342 DOI:10.1039/DT9810001342 |
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Nuclear magnetic resonance spectra of some silyl and trimethylsilyl pseudohalides David E. J. Arnold, Stephen Cradock, E. A. V. Ebsworth, James D. Murdoch, David W. H. Rankin, Donald C. J. Skea, Robin K. Harris and Barry J. Kimber, pp 1349 DOI:10.1039/DT9810001349 |
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Structural studies of group 5B-halide-dithio-ligand complexes. Part 1. Crystal structures of bis(NN-diethyldithiocarbamato)-iodo- and -bromo-bismuth(III) Colin L. Raston, Graham L. Rowbottom and Allan H. White, pp 1352 DOI:10.1039/DT9810001352 |
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Structural studies of group 5B-halide-dithio-ligand complexes. Part 2. Crystal structures of 1 : 1 adducts of bis(NN-diethyldithiocarbamato)iodoantimony(III) with chloroform and molecular iodine Gregory McKie, Colin L. Raston, Graham L. Rowbottom and Allan H. White, pp 1360 DOI:10.1039/DT9810001360 |
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Structural studies of group 5B-halide-dithio-ligand complexes. Part 3. Crystal structure of polymeric (NN-diethyldithiocarbamato)di-iodobismuth(III) Colin L. Raston, Graham L. Rowbottom and Allan H. White, pp 1366 DOI:10.1039/DT9810001366 |
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Structural studies of group 5B-halide-dithio-ligand complexes. Part 4. Crystal structures of bis(tetraethylammonium) di-µ-iodo-bis[(NN-diethyldithiocarbamato)di-iodobismuthate(III)] and a partially brominated analogue Colin L. Raston, Graham L. Rowbottom and Allan H. White, pp 1369 DOI:10.1039/DT9810001369 |
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Structural studies of group 5B-halide-dithio-ligand complexes. Part 5. Crystal structures of pentanuclear [Bi5(S2CNEt2)8X7], X = Cl, Br, or I, and the pyridinium salt of the tetranuclear [Bi4(S2CNEt2)4Br10]2- anion Colin L. Raston, Graham L. Rowbottom and Allan H. White, pp 1372 DOI:10.1039/DT9810001372 |
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Structural studies of group 5B-halide-dithio-ligand complexes. Part 6. Crystal structures of dichloro (NN-diethyldithiocarbamato) tris(pyridine)-bismuth(III)-pyridine (1/1) and its di-iodo-analogue Colin L. Raston, Graham L. Rowbottom and Allan H. White, pp 1379 DOI:10.1039/DT9810001379 |
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Structural studies of Group 5B-halide-dithio-ligand complexes. Part 7. Crystal structures of the 1 : 1 adducts of (NN-diethyldithiocarbamato)-di-iodobismuth(III) with 2,2-bipyridyl and 2,2:6,2-terpyridyl Colin L. Raston, Graham L. Rowbottom and Allan H. White, pp 1383 DOI:10.1039/DT9810001383 |
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Structural studies of Group 5B-halide-dithio-ligand complexes. Part 8. Crystal structure of NN-diethylthiocarbamoylpyridinium pentachloropyridinebismuthate(III) Colin L. Raston, Graham L. Rowbottom and Allan H. White, pp 1389 DOI:10.1039/DT9810001389 |
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Preparation, properties, and structures of bis(O-ethyl dithiocarbonato)-dihalogenotin(IV) and di-µ-thio-bis[bis(O-ethyl dithiocarbonato)tin(IV)] Robert W. Gable, Colin L. Raston, Graham L. Rowbottom, Allan H. White and George Winter, pp 1392 DOI:10.1039/DT9810001392 |
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Cyclopentadienyl-ruthenium and -osmium chemistry. Part 11. Reactions and structures of [RuCl(PPh3)2(-C5H5)] and its trimethyl-phosphine analogue Michael I. Bruce, Fook Sin Wong, Brian W. Skelton and Allan H. White, pp 1398 DOI:10.1039/DT9810001398 |
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Macrocyclic copper(II) chelate derivatives of 2,9-bis(methoxymethyl)-2,9-dimethyl-4,7-dioxadecanedioic and 2,2,9,9-tetramethyl-4,7-dithiadecanedioic acids. The crystal and molecular structures of aqua, pyridine, and triphenylphosphine adducts of [2,9-bis(methoxymethyl)-2,9-dimethyl-4,7-dioxadecanedioato]copper(II) Robert McCrindle, George Ferguson, Alan J. McAlees and Paul J. Roberts, pp 1406 DOI:10.1039/DT9810001406 |
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Synthesis, molecular structure, and nuclear magnetic resonance investigation of the platinanonaborane and diplatinadecaborane cluster compounds, [4,4-(PMe2Ph)2-arachno-4-PtB8H12] and [6,6,9,9-(PMe2-Ph)4-arachno-6,9-Pt2B8H10] Simon K. Boocock, Norman N. Greenwood, Michael J. Hails, John D. Kennedy and Walter S. McDonald, pp 1415 DOI:10.1039/DT9810001415 |
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A new route to isomers of icosaborane(26), B20H26. The use of 115.5-MHz 11B and 11B-{1H} nuclear magnetic resonance spectroscopy for the comparison and characterisation of separated isomers and the identification of three further icosaboranes as 1,2-, 2,5-, and 5,5(or 5,7)-(B10H13)2 Simon K. Boocock, Yvonne M. Cheek, Norman N. Greenwood and John D. Kennedy, pp 1430 DOI:10.1039/DT9810001430 |
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High-spin nickel(II) complexes of penta-aza macrocycles: characterization, electronic spectra, and thermodynamic properties Luigi Fabbrizzi, Mauro Micheloni, Piero Paoletti, Antonio Poggi and Alfred B. P. Lever, pp 1438 DOI:10.1039/DT9810001438 |
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Note. Antimony-121 Mössbauer study of the effects of calcination on the structure of tin-antimony oxides Frank J. Berry and Brian J. Laundy, pp 1442 DOI:10.1039/DT9810001442 |
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Back cover J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100BX023 |
Issue 7
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Front cover J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100FX025 |
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Contents pages J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100FP029 |
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Linear free-energy relationships in the hydrolysis of metal ions. The effect of the ionic medium Nikola B. Mili ,pp 1445 DOI:10.1039/DT9810001445 |
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Mössbauer investigations of some chemical treatments of iron surfaces Frank J. Berry, Michael E. Brett, Paul Bowen and William Jones, pp 1450 DOI:10.1039/DT9810001450 |
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Studies in cyclophosphazenes. Part 11. Geminal amination of (alkylamino)pentachlorocyclotriphosphazenes via a conjugate-base mechanism Zilla Gabay and Jacob M. E. Goldschmidt, pp 1456 DOI:10.1039/DT9810001456 |
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Preparation of tertiary arsine sulphides. Crystal and molecular structures of the adduct of AsMePh2S and P(NMe2)3O Douglas H. Brown, A. Forbes Cameron, Ronald J. Cross and Mary McLaren, pp 1459 DOI:10.1039/DT9810001459 |
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Cation distortion isomerism in three five-co-ordinate diethylenetriamine(di-2-pyridylamine)copper(II) complexes Noel J. Ray, Leslie Hulett, Robert Sheahan and Brian J. Hathaway, pp 1463 DOI:10.1039/DT9810001463 |
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Crystal and molecular structures of [AsPh4][Ln{S2P(OEt)2}4](Ln = La or Er) and their comparison with results obtained in solution from paramagnetic nuclear magnetic resonance data A. Alan Pinkerton and Dieter Schwarzenbach, pp 1470 DOI:10.1039/DT9810001470 |
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Dithiophosphinate complexes of the actinides. Part 1. Preparation and characterisation of complexes of thorium(IV) and the crystal structures of [Th(S2PR2)4], R = Me or C6H11 A. Alan Pinkerton, Anthony E. Storey and Jean-Michel Zellweger, pp 1475 DOI:10.1039/DT9810001475 |
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Rates and activation parameters for solvent exchange with [M(PR3)2-(solvent)2H2]+(M = RhIII or IrIII, R = cyclohexyl or phenyl) cations Oliver W. Howarth, Colin H. McAteer, Peter Moore and George E. Morris, pp 1481 DOI:10.1039/DT9810001481 |
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Highly selective membrane transport of copper(II) ion by synthetic linear oligomer carriers Kazuhiro Maruyama, Hiroshi Tsukube and Takeo Araki, pp 1486 DOI:10.1039/DT9810001486 |
5T2 1A1 and 6A12T2 spin transitions in iron(II) and iron(III) complexes of 2,2-bi-2-imidazoline and related ligandsMichael G. Burnett, Vickie McKee and S. Martin Nelson, pp 1492 DOI:10.1039/DT9810001492 |
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A vibrational spectroscopic study of [Rh4(CO)12] J. Alan Creighton and Brian T. Heaton, pp 1498 DOI:10.1039/DT9810001498 |
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Molecular structure of tris(methylsilyl)amine in the gas phase determined by electron diffraction E. A. V. Ebsworth, Elaine K. Murray, David W. H. Rankin and Heather E. Robertson, pp 1501 DOI:10.1039/DT9810001501 |
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Regioselective formation of peroxyquinolatocobalt(III) complexes in the oxygenation of 2,6-di-t-butylphenols with cobalt(II) Schiff-base complexes Akira Nishinaga, Haruo Tomita, Kanji Nishizawa, Teruo Matsuura, Shunichiro Ooi and Ken Hirotsu, pp 1504 DOI:10.1039/DT9810001504 |
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Redox properties of [IrCl4(PMe2Ph)2] : the synthesis of halide-bridged mixed-metal mixed-valence complexes and the crystal and molecular structure of [(Me3As)ClPd(µ-Cl)2IrCl2(PMe2Ph)2] Clive E. Briant, Keith A. Rowland, Craig T. Webber and D. Michael P. Mingos, pp 1515 DOI:10.1039/DT9810001515 |
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Ring opening in a non-basic medium of 2-methyl-6-nitrobenzothiazole and H-D exchange at the 2-methyl promoted by silver(I) Michele Aresta and Francesco Ciminale, pp 1520 DOI:10.1039/DT9810001520 |
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Metal-to-ligand charge-transfer excited-state photochemistry of [Cr(CO)5(C4H4N2)] and [Cr(CO)4(NC5H4CHNPri)]. The difference between the photochemical behaviour of [Cr(CO)5(C4H4N2)] in solution at 243 K and in an argon matrix at 10 K Roelof W. Balk, Gosse Boxhoorn, Theo L. Snoeck, Gerard C. Schoemaker, Derk. J. Stufkens and Ad Oskam, pp 1524 DOI:10.1039/DT9810001524 |
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Equilibria of some -amino-acids containing sulphur atoms in the chain with metal(II) ions. Part 1. DL-4,4-dithiobis(2-aminobutyric acid) with manganese(II), cobalt(II), and nickel(II) in aqueous solution Francesco Bigoli, Enrico Leporati and Maria Angela Pellinghelli, pp 1531 DOI:10.1039/DT9810001531 |
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The structures and fluxional behaviour of the binary carbonyls; a new approach. Part 3. The fluxional behaviour of [Fe3(CO)11L], L = PR3 or P(OR)3 Robert E. Benfield, Paul D. Gavens, Brian F. G. Johnson, Martin J. Mays, Silvo Aime, Luciano Milone and Domenico Osella, pp 1535 DOI:10.1039/DT9810001535 |
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Reactivity of co-ordination compounds in the solid state. Part 1. Mixed-ligand complexes of oxalate and 2,2-bipyridlyl with copper(II), their preparation, interconversion, and novel solid-state reactivity Paul O'Brien, pp 1540 DOI:10.1039/DT9810001540 |
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Tetracarbonyl diazaphosphole complexes of group 6B metals: the role of steric effects Graziano Baccolini, Luigi Busetto and Elisabetta Foresti, pp 1544 DOI:10.1039/DT9810001544 |
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Crystal structure and carbon-13 nuclear magnetic resonance spectrum of [NMe4]2[Fe4S4(SCH2CH2OH)4] and electron spin resonance spectrum of [Fe4S4(SCH2CH2OH)4]3- in aqueous solution George Christou, C. David Garner, Michael G. B. Drew and Richard Cammack, pp 1550 DOI:10.1039/DT9810001550 |
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A structural profile of the bis(2,2-bipyridyl)monochlorocopper(II) cation. Crystal structures of bis(2,2-bipyridyl)monochlorocopper(II) perchlorate and the nitrate trihydrate W. David Harrison, Declan M. Kennedy, Mary Power, Robert Sheahan and Brian J. Hathaway, pp 1556 DOI:10.1039/DT9810001556 |
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Nucleophilic attack on olefins co-ordinated to platinum. Part 3. Effect of substituents on the olefins on the formation of 2-ammonioethanide compounds (H3NCHRCHR-Pt), of four-membered ring complexes, and of five-co-ordinate species Michael Green, Jamil K. K. Sarhan and Ibrahim M. Al-Najjar, pp 1565 DOI:10.1039/DT9810001565 |
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Transition metal-carbon bonds. Part 50. Conversion of mer-[IrCl3-(PMe2R)3](R = Me or Ph) to [IrCl2(CH2PMeR)(PMe2R)2](three-membered ring) by the action of base: crystal structure of [IrCl2(CH2PMePh)(PMe2Ph)2] Subhi Al-Jibori, Christopher Crocker, Walter S. McDonald and Bernard L. Shaw, pp 1572 DOI:10.1039/DT9810001572 |
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The mechanism and kinetics of the substitution of azide, thiocyanate, and cyanide ions in aquopentacyanocobaltate(III) and pentacyanohydroxocobaltate(III) Michael G. Burnett and W. Matthew Gilfillan, pp 1578 DOI:10.1039/DT9810001578 |
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Paramagnetic carbenemetal complexes. Part 2. Synthesis and spectroscopic studies of stable electron-rich olefin-derived paramagnetic carbenecarbonyl- and carbenenitrosyl-iron(I) complexes Michael F. Lappert, Jonathan J. MacQuitty and Peter L. Pye, pp 1583 DOI:10.1039/DT9810001583 |
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Metallocene derivatives of early transition metals. Part 4. Chemistry of the complexes [M(-C5H5)2RR][M = Ti, Zr, or Hf; R = CH2MMe3(M= C, Si, Ge, or Sn) or CH(SiMe3)2; R= Cl or alkyl] and the X-ray structures of [Zr(-C5H5)2(CH2MMe3)2](M= C or Si) John Jeffery, Michael F. Lappert, N. Tuyet Luong-Thi, Maurice Webb, Jerry L. Atwood and William E. Hunter, pp 1593 DOI:10.1039/DT9810001593 |
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Aluminium-27 nuclear magnetic resonance studies of the hydrolysis of aluminium(III). Part 2. Gel-permeation chromatography J. W. Akitt and Alan Farthing, pp 1606 DOI:10.1039/DT9810001606 |
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Aluminium-27 nuclear magnetic resonance studies of the hydrolysis of aluminium(III). Part 3. Stopped-flow kinetic studies J. W. Akitt, Alan Farthing and Oliver W. Howarth, pp 1609 DOI:10.1039/DT9810001609 |
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Aluminium-27 nuclear magnetic resonance studies of heteropolyanions containing aluminium as heteroatom J. W. Akitt and Alan Farthing, pp 1615 DOI:10.1039/DT9810001615 |
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Aluminium-27 nuclear magnetic resonance studies of the hydrolysis of aluminium(III). Part 4. Hydrolysis using sodium carbonate J. W. Akitt and Alan Farthing, pp 1617 DOI:10.1039/DT9810001617 |
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Aluminium-27 nuclear magnetic resonance studies of the hydrolysis of aluminium(III). Part 5. Slow hydrolysis using aluminium metal J. W. Akitt and Alan Farthing, pp 1624 DOI:10.1039/DT9810001624 |
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Preparation of the isocyanide complexes trans-[ReCl(CNR)(dppe)2](R = Me or But) and their reactions with acid to give carbyne complexes. X-Ray crystal structure of trans-[ReCl(CNHMe)(dppe)2][BF4] Armando J. L. Pombeiro, Maria Fernanda N. N. Carvalho, Peter B. Hitchcock and Raymond L. Richards, pp 1629 DOI:10.1039/DT9810001629 |
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Reactions of hydrogenated thiamine derivatives with K2[MX4], where M is PdII or PtII and X is Cl or Br Nick Hadjiliadis and John Markopoulos, pp 1635 DOI:10.1039/DT9810001635 |
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Dynamic nuclear magnetic resonance and X-ray diffraction studies of tris(diphenylthiophosphoryl)methane and some related compounds Ian J. Colquhoun, William McFarlane, Jean-Marie Bassett and Samuel O. Grim, pp 1645 DOI:10.1039/DT9810001645 |
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Synthesis, reactivity, and crystal and molecular structures of [µ-1,4-bis(diphenylphosphino)butane]-dicarbonylbis-(cyclopentadienyl)-dirhodium(I) Felice Faraone, Giuseppe Bruno, Giuseppe Tresoldi, Giovanni Faraone and Gabriella Bombieri, pp 1651 DOI:10.1039/DT9810001651 |
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Hydrogen-1 and carbon-13 nuclear magnetic resonance studies of gold (I) thiomalate (Myocrisin) in aqueous solution: dependence of the solution structure on pH and ionic strength Anvarhusein A. Isab and Peter J. Sadler, pp 1657 DOI:10.1039/DT9810001657 |
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Letters C. David Garner and Richard M. Miller, pp 1664 DOI:10.1039/DT9810001664 |
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Back cover J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100BX027 |
Issue 8
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Front cover J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100FX029 |
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Contents pages J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100FP033 |
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Co-ordination properties of N-protected amino-acids. Solution and solid-state behaviour of bis(benzyloxycarbonyl-L-tryptophanato)-nickel(II) and its mixed complexes Renata Battini, Giovanna Gavioli Battistuzzi, Giulia Grandi, Ledi Menabue, Gian Carlo Pellacani, Monica Saladini and Anna Bonamartini Corradi, pp 1665 DOI:10.1039/DT9810001665 |
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Metal-ion-controlled transamination in the synthesis of macrocyclic Schiff-base ligands. Part 1. Reactions of 2,6-diacetylpyridine and dicarbonyl compounds with 3,6-dioxaoctane-1,8-diamine S. Martin Nelson, C. Victor Knox, Malachy McCann and Michael G. B. Drew, pp 1669 DOI:10.1039/DT9810001669 |
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Metal-ion-controlled transamination in the synthesis of macrocyclic Schiff-base ligands. Part 2. Stepwise synthesis, ring expansion/contraction, and the crystal and molecular structure of a ten-co-ordinate barium(II) complex Michael G. B. Drew, Jane Nelson and S. Martin Nelson, pp 1678 DOI:10.1039/DT9810001678 |
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Synthesis of some pentagonal-bipyramidal complexes of manganese(II), iron(II), cobalt(II), nickel(II), copper(II), and zinc(II) with a heptadentate Schiff-base ligand and the crystal and molecular structures of a copper(II) complex Michael G. B. Drew, Jane Nelson and S. Martin Nelson, pp 1685 DOI:10.1039/DT9810001685 |
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Intramolecular ligand rearrangement in the isomerisation of a seven-co-ordinate to a six-co-ordinate nickel(II) complex of a multidentate Schiff base. The crystal and molecular structures of the six-co-ordinate product Michael G. B. Drew, Jane Nelson and S. Martin Nelson, pp 1691 DOI:10.1039/DT9810001691 |
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Structural and mechanistic studies of co-ordination compounds. Part 30. Synthesis and characterization of some octahedral halogenoamine complexes of osmium(III) Chung-Kwong Poon, Chi-Ming Che and Tin-Wu Tang, pp 1697 DOI:10.1039/DT9810001697 |
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Small molecule analogues for the specific metal-binding site of lactoferrin. Part 2. Phenolato-complexes of copper(II) and the nature of the charge-transfer transition in the visible region Eric W. Ainscough, Alistair G. Bingham, Andrew M. Brodie, June M. Husbands and Jeffrey E. Plowman, pp 1701 DOI:10.1039/DT9810001701 |
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Spectrochemistry of solutions. Part 14. Raman and infrared spectra of thiocyanatosilver(I) complexes in some non-aqueous solutions Peter Gans, J. Bernard Gill and D. Peter Fearnley, pp 1708 DOI:10.1039/DT9810001708 |
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Is the angular overlap model chemically significant? Malcolm Gerloch and R. Guy Woolley, pp 1714 DOI:10.1039/DT9810001714 |
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Thermal degradation of dimethylvinylarsine in triosmium clusters to give bridging vinyl, vinylidene, and acetylene ligands Christopher J. Cooksey, Antony J. Deeming and Ian P. Rothwell, pp 1718 DOI:10.1039/DT9810001718 |
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Fast reactions at planar four-co-ordinate complexes. Part 4. The reaction of chelate dichloropalladium(II) complexes with some bidentate ligands Matteo Cusumano, Giovanni Guglielmo and Vittorio Ricevuto, pp 1722 DOI:10.1039/DT9810001722 |
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Evidence for dimer formation of nitrosyl(meso-2,3,7,8,12,13,17,18-octaethyl-5-nitroporphyrinato)iron(II) and its implication in the interpretation of the electron spin resonance spectrum of the nitrosyl-haemoglobin-salicylate system Hideo Kon, Makoto Chikira and Kevin M. Smith, pp 1726 DOI:10.1039/DT9810001726 |
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Carbon-13 nuclear magnetic resonance in isotopically enriched high-spin iron(III) porphyrins: -electron spin distribution Joël Mispelter, Michel Momenteau and Jean-Marc Lhoste, pp 1729 DOI:10.1039/DT9810001729 |
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Electron spin resonance behaviour of the [Fe3Pt3(CO)15]- carbonyl cluster anion Giuliano Longoni and Franca Morazzoni, pp 1735 DOI:10.1039/DT9810001735 |
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Reactions and properties of some trimethyleneplatinum(IV) complexes. Part 11. Platinacyclobutanes derived from methylcyclopropane Razak J. Al-Essa, Richard J. Puddephatt, Duncan C. L. Perkins, Melvyn C. Rendle and Charles F. H. Tipper, pp 1738 DOI:10.1039/DT9810001738 |
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Copper co-ordination to thioether ligands. Chemical, spectroscopic, and crystallographic studies on copper(I) complexes of 2-(3,3-dimethyl-2-thiabutyl)pyridine and the 2-(3,3-dimethyl-2-thiabutyl)pyridinium cation Eric W. Ainscough, Edward N. Baker, Andrew M. Brodie, Nigel G. Larsen and Kevin L. Brown, pp 1746 DOI:10.1039/DT9810001746 |
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Spectroscopic and structural investigation of two N-benzylpiperazinium tetrachlorocuprates(II), one hemihydrate and one anhydrous: two compounds containing unequally flattened [CuCl4]2- tetrahedra Luciano Antolini, Ledi Menabue, Gian Carlo Pellacani, Monica Saladini, Giuseppe Marcotrigiano and William Porzio, pp 1753 DOI:10.1039/DT9810001753 |
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Electronic, infrared, and resonance-Raman spectroscopic study of pyridine complexes of ruthenium-(II) and -(III) Robin J. H. Clark and Martin J. Stead, pp 1760 DOI:10.1039/DT9810001760 |
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Notes. Crystal structure of sodium dihydrogen triacetate Angelo Perotti and Vittorio Tazzoli, pp 1768 DOI:10.1039/DT9810001768 |
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Crystal structure and infrared spectrum of anhydrous guanidinium copper(II) carbonate Jeffrey C. Dyason, Peter C. Healy, Brian W. Skelton and Allan H. White, pp 1770 DOI:10.1039/DT9810001770 |
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Back cover J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100BX031 |
Issue 9
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Front cover J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100FX033 |
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Contents pages J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100FP037 |
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Crystal and molecular structure of bis(N-allylsalicylideneiminato)-nickel(II) and -copper(II) Subhash C. Bhatia, Jag M. Bindlish, Agya R. Saini and Prem C. Jain, pp 1773 DOI:10.1039/DT9810001773 |
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Kinetics of the formation and dissociation of pentacyanoferrate(II) complexes of cysteine, penicillamine, glutathione, and 2-mercaptoethylamine Donal H. Macartney and Alexander McAuley, pp 1780 DOI:10.1039/DT9810001780 |
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Extended Hückel molecular-orbital calculations on dodecahedral metalloboranes which do not conform to the polyhedral skeletal electron-pair theory David N. Cox, D. Michael P. Mingos and Roald Hoffmann, pp 1788 DOI:10.1039/DT9810001788 |
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Synthesis and structure of bis(diethyldithiocarbamato)nitridotechnetium(V): a technetium-nitrogen triple bond John Baldas, John Bonnyman, Peter M. Pojer, Geoffrey A. Williams and Maureen F. Mackay, pp 1798 DOI:10.1039/DT9810001798 |
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Crystal structure and infrared and Raman spectra of tetramethylammonium di-µ-fluoro-bis[aquadifluoro-oxovanadate(IV)] Peter Bukove, Svetozar Mili ev, Alojz Dem ar and Ljubo Goli ,pp 1802 DOI:10.1039/DT9810001802 |
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Studies on the oxidation of iron(II) ion during the formation of Fe3O4 and -FeO(OH) by air oxidation of Fe[OH]2 suspensions Yutaka Tamaura, Perlas V. Buduan and Takashi Katsura, pp 1807 DOI:10.1039/DT9810001807 |
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Polarised single-crystal electronic absorption spectra of tetraphenylarsonium tetrahalogenonitrido-osmate(VI) compounds and the crystal and molecular structures of tetraphenylarsonium tetrabromonitrido-osmate(VI) David Collison, C. David Garner, Frank E. Mabbs, John A. Salthouse and Trevor J. King, pp 1812 DOI:10.1039/DT9810001812 |
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Polarised single-crystal electronic absorption spectra of tetraphenylarsonium tetrahalogenonitridoruthenate(VI) compounds and the crystal and molecular structures of tetraphenylarsonium tetrabromonitrido-ruthenate(VI) David Collison, C. David Garner, Frank E. Mabbs and Trevor J. King, pp 1820 DOI:10.1039/DT9810001820 |
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Ligand substitution in bis(N-alkylsalicylideneiminato)copper(II) complexes: comparison of activation and transfer data obtained from solvent mixtures Horst Elias, Horst Muth, Beate Niedernhöfer and Klaus J. Wannowius, pp 1825 DOI:10.1039/DT9810001825 |
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A tin-119 Mössbauer study of the phase transitions in SnF2 Thomas Birchall, Georges Dénès, Krzysztof Ruebenbauer and Jean Pannetier, pp 1831 DOI:10.1039/DT9810001831 |
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Spin density and manganese electronic structure in phthalocyaninatomanganese(II) Brian N. Figgis, Geoffrey A. Williams, J. Bruce Forsyth and Ronald Mason, pp 1837 DOI:10.1039/DT9810001837 |
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Nuclear magnetic resonance investigations of configurational nonrigidity in dinuclear platinum(IV) complexes. Part 3. Novel fluxional rearrangements in [(PtXMe3)2(SCHRSCHRECHR)](X = Cl, Br, or I; R = H or Me; E = S or CH2) complexes Edward W. Abel, Martin Booth, Gary King, Keith G. Orrell, Graham M. Pring and Vladimir  ik,pp 1846 DOI:10.1039/DT9810001846 |
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Ketoximato-complexes. Part 3. Structure and properties of tris chelates of cobalt(III), iron(II), and ruthenium(II) Claude Bremard, Guy Nowogrocki and Stéphane Sueur, pp 1856 DOI:10.1039/DT9810001856 |
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Kinetics of the oxidation of hydrogen peroxide by bis(2,2-bipyridine)-silver(II) ions Malcolm P. Heyward and Cecil F. Wells, pp 1863 DOI:10.1039/DT9810001863 |
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Bi-copper(I) and bi-copper(II) complexes of a 30-membered macrocyclic ligand: the inclusion of substrate molecules and the crystal and molecular structures of a µ-hydroxo- and a µ-imidazolato-complex Michael G. B. Drew, Malachy McCann and S. Martin Nelson, pp 1868 DOI:10.1039/DT9810001868 |
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Solution behaviour of some benzyne complexes of osmium and the X-ray crystal structure of µ3-benzyne-1,1,1,2,2,2,3,3,3-nonacarbonyl-µ-dimethylarsino-µ-hydrido-triosmium(2Os-Os) Antony J. Deeming, Ian P. Rothwell, Michael B. Hursthouse and J. D. Julius Backer-Dirks, pp 1879 DOI:10.1039/DT9810001879 |
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Studies on transition-metal cyano-complexes. Part 3. Heptacyano-complexes of tungsten, molybdenum, and vanadium, and a hydrido-heptacyano-complex of tungsten Ana-Maria Soares and William P. Griffith, pp 1886 DOI:10.1039/DT9810001886 |
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Trimethylphosphine complexes of molybdenum, tungsten, niobium, and tantalum. X-Ray crystal structures of di-µ-hydrido-dihydridohexakis-(trimethylphosphine)dimolybdenum(II)(Mo-Mo) and of µ-dimethylphosphido-µ-hydrido-tetrahydridopentakis(trimethylphosphine)ditungsten(II, IV)(W-W) Kwok W. Chiu, Richard A. Jones, Geoffrey Wilkinson, Anita M. R. Galas and Michael B. Hursthouse, pp 1892 DOI:10.1039/DT9810001892 |
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Further studies on the interaction of nitric oxide with transition-metal alkyls A. Robert Middleton and Geoffrey Wilkinson, pp 1898 DOI:10.1039/DT9810001898 |
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Friedel-Crafts acylation of tricarbonyl(cyclo-octatetraene)iron. Preparation and reactions of (8-acylbicyclo[3.2.1]octadienylium)tricarbonyliron hexafluorophosphates Andrew D. Charles, Pietro Diversi, Brian F. G. Johnson and Jack Lewis, pp 1906 DOI:10.1039/DT9810001906 |
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Reactions of metal carbonyl derivatives. Part 25. The bridging properties of tetraethyl diphosphite, (EtO)2POP(OEt)2 A. Louis du Preez, Isaac L. Marais, Raymond J. Haines, Alan Pidcock and Mohammad Safari, pp 1918 DOI:10.1039/DT9810001918 |
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Studies of mixed-metal hydroxy-bridged complexes. Part 1. Complexes with bis(ethylenediamine)dihydroxocobalt(III) as ligand Roderick D. Cannon and Soontaree Benjarvongkulchai, pp 1924 DOI:10.1039/DT9810001924 |
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Studies of phosphazenes. Part 13. Thermal rearrangement reactions of some methoxycyclophosphazenes K. S. Dhathathreyan, S. S. Krishnamurthy, A. R. Vasudeva Murthy, Robert A. Shaw and Michael Woods, pp 1928 DOI:10.1039/DT9810001928 |
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Crystal and molecular structures of the isobutene insertion product of endo-hexafluoroacetylacetonato(methoxytetraphenylbutadienyl)-palladium(II) Winnie Wong-Ng and Stanley C. Nyburg, pp 1935 DOI:10.1039/DT9810001935 |
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Synthesis of zerovalent bis(-arene) compounds of zirconium, hafnium, niobium, tantalum, and tungsten using the metal vapours F. Geoffrey N. Cloke and Malcolm L. H. Green, pp 1938 DOI:10.1039/DT9810001938 |
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Ring reversal, sulphur inversion, and 1,3-metal shifts in sulphur-containing six-membered-ring complexes of chromium and tungsten carbonyls Edward W. Abel, Martin Booth, Keith G. Orrell and Graham M. Pring, pp 1944 DOI:10.1039/DT9810001944 |
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Crystal and molecular structure of the {2,6-bis[1-(2-imidazol-4-ylethylimino)ethyl]pyridine}-zinc(II) and -copper(II) cations: five-co-ordinate relatives of a copper(I) oxygen carrier James D. Korp, Ivan Bernal, Connie L. Merrill and Lon J. Wilson, pp 1951 DOI:10.1039/DT9810001951 |
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Preparation of alkyl-substituted partial trimethylsilyl silicates from olivine Kazuyuki Kuroda, Tetsuhiro Koike and Chuzo Kato, pp 1957 DOI:10.1039/DT9810001957 |
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Equilibria of some -amino-acids containing sulphur atoms in the chain with metal(II) ions. Part 2. SS-methylenebis(L-cysteine) with cobalt(II), nickel(II), and zinc(II) in aqueous solution Francesco Bigoli, Enrico Leporati and Maria Angela Pellinghelli, pp 1961 DOI:10.1039/DT9810001961 |
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Iron(II) complexes of a potentially quinquedentate macrocyclic ligand having an N3S2 donor set and the crystal and molecular structures of a high-spin (S= 2) complex and a low-spin (S= 0) complex Colin Cairns, S. Martin Nelson and Michael G. B. Drew, pp 1965 DOI:10.1039/DT9810001965 |
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Hydrazido(2-)-complexes as intermediates in the conversion of ligating dinitrogen into ammonia and hydrazine Stewart N. Anderson, Martin E. Fakley, Raymond L. Richards and Joseph Chatt, pp 1973 DOI:10.1039/DT9810001973 |
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Alkyne complexes of platinum. Part 6. The synthesis of compounds containing platinacyclopenta-2,4-diene and diplatinacyclohexa-2,5-diene rings Neil M. Boag, Gilson H. M. Dias, Michael Green, John L. Spencer, F. Gordon A. Stone and Jose Vicente, pp 1981 DOI:10.1039/DT9810001981 |
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Crystal structures of silyl acetate at 150 K and methyl acetate at 145 K, and the molecular structure of silyl acetate in the gas phase Michael J. Barrow, Stephen Cradock, E. A. V. Ebsworth and David W. H. Rankin, pp 1988 DOI:10.1039/DT9810001988 |
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Characterisation of cationic co-ordination complexes using field desorption mass spectrometry David E. Games, John L. Gower and Leon A. P. Kane-Maguire, pp 1994 DOI:10.1039/DT9810001994 |
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Pentamethylcyclopentadienyl-rhodium and -iridium complexes. Part 29. Syntheses and X-ray structure determinations of [{Rh(C5Me5)}2(OH)3]OH·11H2O and [{lr(C5Me5)}2(OH)3]O2CMe·14H2O and related complexes Andrew Nutton, Pamela M. Bailey and Peter M. Maitlis, pp 1997 DOI:10.1039/DT9810001997 |
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Pentamethylcyclopentadienyl-rhodium and -iridium complexes. Part 30. Trimethylphosphine-chloro-, -acetato-, and -hydrido-complexes and related compounds of (hexamethylbenzene)ruthenium Kiyoshi Isobe, Pamela M. Bailey and Peter M. Maitlis, pp 2003 DOI:10.1039/DT9810002003 |
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Reduction of nitroamine (NH2NO2) by vanadium(II) and chromium(II) in acid solution Martin N. Hughes, Monika Okolow-Zubkowska and Helen L. Wallis, pp 2009 DOI:10.1039/DT9810002009 |
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Notes. Crystal structure of biphenyl-2,2-diyltriphenylantimony Peter L. Millington and D. Bryan Sowerby, pp 2011 DOI:10.1039/DT9810002011 |
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Heteronuclear two-dimensional nuclear magnetic resonance: decaborane Ian J. Colquhoun and William McFarlane, pp 2014 DOI:10.1039/DT9810002014 |
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Reaction of ethylene with [Ru3(CO)12] and the dynamic processes of [Ru3H2(CO)9(C2R2)](R = H, Me, and Et) John Evans and Gregory S. McNulty, pp 2017 DOI:10.1039/DT9810002017 |
Reaction of di-iodonitrosyl[tris(3,5-dimethylpyrazolyl)borato]-molybdenum with , -alkanediols, 2-chloro-, and 2-methoxy-ethanolGianfranco Denti, Jon A. McCleverty and Andrzej W  odarczyk,pp 2021 DOI:10.1039/DT9810002021 |
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Back cover J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100BX035 |
Issue 10
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Front cover J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100FX037 |
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Contents pages J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100FP043 |
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Reaction of 4-methylpent-2-yne with dodecacarbonyltriruthenium. The structure of a novel alkyne dimerization dehydrogenation product Edward Rosenberg, Silvio Aime, Luciano Milone, Enrico Sappa, Antonio Tiripicchio and Anna Maria Manotti Lanfredi, pp 2023 DOI:10.1039/DT9810002023 |
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Crystal structure and electronic properties of bis(2,2-bipyridyl)-thiocyanatocopper(II) tetrafluoroborate Suresh Tyagi and Brian J. Hathaway, pp 2029 DOI:10.1039/DT9810002029 |
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Solubility of salts of hexachlororhenate(IV) ions with complex cations in water and in water + alcohol mixtures: free energies of transfer of the complex ions Ibrahim M. Sidahmed and Cecil F. Wells, pp 2034 DOI:10.1039/DT9810002034 |
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ortho-Metallation products of phenol and aniline with dodecacarbonyl-triosmium. X-Ray crystal structure of [Os3H2(CO)9(NHC6H3F)] Kazi A. Azam, Antony J. Deeming, Ian P. Rothwell, Michael B. Hursthouse and J. D. Julius Backer-Dirks, pp 2039 DOI:10.1039/DT9810002039 |
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Crystal and molecular structure of sodium µ-(imidazol-1-yl-NN)-bis-[(glycylglycinato-NNO)cuprate(II)] hexahydrate: structure-magnetism relationship in imidazolate-bridged binuclear copper(II) complexes Keiji Matsumoto, Shun'ichiro Ooi, Yasuo Nakao, Wasuke Mori and Akitsugu Nakahara, pp 2045 DOI:10.1039/DT9810002045 |
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Syntheses of cationic tri- and di-carbonyl complexes of manganese(I) with diphosphines from the appropriate neutral bromocarbonyls Francisco Bombin, Gabino A. Carriedo, Jesus A. Miguel and Victor Riera, pp 2049 DOI:10.1039/DT9810002049 |
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Copper co-ordination to thioether ligands. Spectroscopic studies of dimeric copper(II) complexes of 2-(3,3-dimethyl-2-thiabutyl)pyridine and the crystal structure of di-µ-bromo-bis{bromo[2-(3,3-dimethyl-2-thiabutyl)pyridine-NS]copper(II)} Eric W. Ainscough, Edward N. Baker, Andrew M. Brodie and Nigel G. Larsen, pp 2054 DOI:10.1039/DT9810002054 |
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Redox behaviour of triangular platinum-cobalt clusters. Electrochemically induced generation of the tetranuclear cluster [Pt2Co2(µ-Co)3(CO)5(PPh3)2] Paul Lemoine, Alain Giraudeau, Maurice Gross, Robert Bender and Pierre Braunstein, pp 2059 DOI:10.1039/DT9810002059 |
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Hydrolysis of imines: kinetics and mechanism of spontaneous acid-, base-, and metal ion-induced hydrolysis of N-salicylidene-2-aminothiazole Anadi C. Dash, Bhaskar Dash and Somnath Praharaj, pp 2063 DOI:10.1039/DT9810002063 |
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Crystal structure and electronic properties of bis(2,2-bipyridyl)-nitratocopper(II) nitrate monohydrate Richard J. Fereday, Peter Hodgson, Suresh Tyagi and Brian J. Hathaway, pp 2070 DOI:10.1039/DT9810002070 |
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Lanthanide ethylenediaminetetra-acetate chelates as aqueous shift reagents: evidence for effective axial symmetry in bidentate cytidine 5-monophosphate and alanine complexes A. Dean Sherry, Cynthia A. Stark, José R. Ascenso and Carlos F. G. C. Geraldes, pp 2078 DOI:10.1039/DT9810002078 |
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Stereochemical role of lone pairs in main-group elements. Part 2. Structure and bonding in trichloro(tetramethylthiourea)antimony(III) studied by means of X-ray crystallography and antimony-121 Mössbauer spectroscopy Edward Hough and David G. Nicholson, pp 2083 DOI:10.1039/DT9810002083 |
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Interaction of t-butyl isocyanide with methyl compounds of tungsten, rhenium, zirconium, titanium, and tantalum. The X-ray crystal structures of W-N(But)CMe2(Me)(NBut)[N(But)CMeCMe2] and its hydrogen chloride adduct. t-Butyl isocyanide complexes of molybdenum(0), ruthenium(II), and rhodium(I) Kwok W. Chiu, Richard A. Jones, Geoffrey Wilkinson, Anita M. R. Galas and Michael B. Hursthouse, pp 2088 DOI:10.1039/DT9810002088 |
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Characterisation of two-, three-, and four-co-ordinate gold(I) complexes by 197Au Mössbauer and 31P-{1H} nuclear magnetic resonance spectroscopy R. V. ( Dick) Parish, Owen Parry and Charles A. McAuliffe,pp 2098 DOI:10.1039/DT9810002098 |
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Structural studies on the caesium alums, CsMIII[SO4]2·12H2O James K. Beattie, Stephen P. Best, Brian W. Skelton and Allan H. White, pp 2105 DOI:10.1039/DT9810002105 |
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Patterns of nucleophilic attack on ethene complexes of ruthenium(II) Martin Stephenson and Roger J. Mawby, pp 2112 DOI:10.1039/DT9810002112 |
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Phosphite complexes of copper(II) carboxylates and their derivatives. Crystal structure of penta-µ-acetato-bis(triethyl phosphite)tricopper-(I,II) Roy L. Beddoes, Joseph A. Connor, Danuta Dubowski, Anthony C. Jones, Owen S. Mills and Raymond Price, pp 2119 DOI:10.1039/DT9810002119 |
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Synthesis, reactivity, and electrochemical behaviour of new five-co-ordinate nitrosyl cobalt complexes Gabriele Albertin, Emilio Bordignon, Gian Antonio Mazzocchin, Angelo A. Orio and Renato Seeber, pp 2127 DOI:10.1039/DT9810002127 |
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Evidence for asymmetrical cleavage of halide-bridged platinum(II) complexes by nucleophiles Ronald J. Cross and Ian G. Phillips, pp 2132 DOI:10.1039/DT9810002132 |
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Reactions of methylmercury(II), mercury(II), and zinc(II) ions with 2-methyl-2-(2-pyridyl)thiazolidine, including stopped-flow rapid-scanning spectrophotometric studies Terence J. Kemp, Paul A. Lampe, Peter Moore and Geoffrey R. Quick, pp 2137 DOI:10.1039/DT9810002137 |
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Deuteriation of an asymmetric short hydrogen bond. X-Ray crystal structure of KF·(CH2CO2D)2 John Emsley, Deborah J. Jones and Reiko Kuroda, pp 2141 DOI:10.1039/DT9810002141 |
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Notes. The acid strength of iodine cyanide Christian Laurence and Michele Queignec-Cabanetos, pp 2144 DOI:10.1039/DT9810002144 |
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Back cover J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100BX039 |
Issue 11
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Front cover J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100FX041 |
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Contents pages J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100FP047 |
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Optically active complexes of Schiff bases. Part 6. Palladium(II) and platinum(II) complexes with quadridentate Schiff bases of salicylaldehyde Edoardo Cesarotti, Alessandro Pasini and Renato Ugo, pp 2147 DOI:10.1039/DT9810002147 |
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Co-ordination chemistry of higher oxidation states. Part 2. Neutral and cationic complexes of platinum(IV) with bi- and multi-dentate ligands David J. Gulliver, William Levason and Kenneth G. Smith, pp 2153 DOI:10.1039/DT9810002153 |
Photolytic homolysis of the metal-carbon (sp3 or sp2) bond of alkyl or acyl transition-metal complexes: an electron spin resonance study using spin trapping; and a note on aminyl oxides [MLn{N( )R}][MLn= Ru(CO)4(SiMe3), Os(CO)4(SiMe3), or Fe(-C3H5)(CO)3; R = aryl]Andrew Hudson, Michael F. Lappert, Peter W. Lednor, Jonathan J. MacQuitty and Brian K. Nicholson, pp 2159 DOI:10.1039/DT9810002159 |
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Reactions of stable [PtCl2(2-olefin)(-di-imine)] complexes. Retention of the five-co-ordinate structure upon halogen exchange and ligand substitution with olefins, -di-imines, and N,N-disubstituted 1,2-diaminoethanes Henk van der Poel, Gerard van Koten and Gerard C. van Stein, pp 2164 DOI:10.1039/DT9810002164 |
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Substitution of acetonitrile co-ordinated to iron(II) by trimethyl phosphite: a kinetic study of the formation and disappearance of [Fe(NCMe)4{P(OMe)3}2]2+ James H. Cameron, A. Graham Lappin, John M. Winfield and Alexander McAuley, pp 2172 DOI:10.1039/DT9810002172 |
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Synthesis and characterisation of the reaction products from bis(thiosalicylohydrazidato)nickel(II) in base and acid solution Prasanta K. Biswas and Nirmalendu Ray Chaudhuri, pp 2176 DOI:10.1039/DT9810002176 |
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Electron-gain and -loss centres in irradiated periodates: an electron spin resonance study Martyn C. R. Symons and Shuddhodan P. Mishra, pp 2183 DOI:10.1039/DT9810002183 |
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Tetrasulphur dinitride; its preparation, crystal structure, and solid-state decomposition to give poly(sulphur nitride) Ronald W. H. Small, Arthur J. Banister and Zdenek V. Hauptman, pp 2188 DOI:10.1039/DT9810002188 |
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Conformations of diphosphinoamines; variable-temperature nuclear magnetic resonance and X-ray crystallographic studies Rodney Keat, Ljubica Manojlovi -Muir, Kenneth W. Muir and David S. Rycroft,pp 2192 DOI:10.1039/DT9810002192 |
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Photochemistry of tricarbonyl(-cyclopentadienyl)methylmolybdenum in frozen gas matrices at 12 K. Infrared spectroscopic evidence for the formation of dicarbonyl(-cyclopentadienyl)methylmolybdenum and dicarbonyl(-cyclopentadienyl)(dinitrogen)methylmolybdenum Khalil A. Mahmoud, Ramaier Narayanaswamy and Antony J. Rest, pp 2199 DOI:10.1039/DT9810002199 |
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Cyclopentadienyl-ruthenium and -osmium chemistry. Part 15. Some cyanocarbon and cyanonitrogen complexes: crystal and molecular structures of [Ru{NCC(CN)C(CN)C(CN)2}{P(OMe)3}(PPh3)(-C5H5)] Michael I. Bruce, Robert C. Wallis, Brian W. Skelton and Allan H. White, pp 2205 DOI:10.1039/DT9810002205 |
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Palladium(II) complexation of ambidentate cis-s-cis-enaminones: synthesis of some bis(4-anilinopent-3-en-2-onato)- and bis(3-amino-1-phenylbut-2-en-1-onato)-complexes of palladium(II) and X-ray crystal structure of bis[4-(2-bromoanilino)pent-3-en-2-onato]palladium(II) Hideo Iida, Yoshifumi Yuasa, Chihiro Kibayashi and Yoichi Iitaka, pp 2212 DOI:10.1039/DT9810002212 |
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Formation of aluminium-bearing ferrite in aqueous suspension by air oxidation Kazuo Ito, Tadao Kanzaki, Yutaka Tamaura and Takashi Katsura, pp 2217 DOI:10.1039/DT9810002217 |
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Organosulphur-transition-metal chemistry. Part 5. Face bonding of cycloheptatrienyl and cyclo-octatetraene ligands in sulphur-ruthenium clusters: crystal and molecular structure of [Ru3(CO)6(µ3-SBut){µ3-(7-C7H7)}] T. Anthony Cresswell, Judith A. K. Howard, Fiona G. Kennedy, Selby A. R. Knox and Hubert Wadepohl, pp 2220 DOI:10.1039/DT9810002220 |
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Organosulphur-transition-metal chemistry. Part 6. Reactions of cyclo-octatetraenyl and cycloheptatrienyl thioethers with metal carbonyls Susan C. Carleton, Fiona G. Kennedy and Selby A. R. Knox, pp 2230 DOI:10.1039/DT9810002230 |
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Organosulphur-transition-metal chemistry. Part 7. Sulphur inversion in dimolybdenum complexes: crystal and molecular structure of [Mo2(CO)2{P(OMe)3}(µ-SBut)3(-C7H7)] Ian B. Benson, Selby A. R. Knox, Pamela J. Naish and Alan J. Welch, pp 2235 DOI:10.1039/DT9810002235 |
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Europium-151 Mössbauer spectra of some orthorhombic perovskites Terence C. Gibb, pp 2245 DOI:10.1039/DT9810002245 |
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Products of the pyrolysis of [Os3(CO)11{P(OMe)3}]; the molecular and crystal structure of [Os5C(CO)13H{OP(OMe)2}{P(OMe)3}] Juan M. Fernandez, Brian F. G. Johnson, Jack Lewis and Paul R. Raithby, pp 2250 DOI:10.1039/DT9810002250 |
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Electron spin resonance studies of electron addition to bis(cyclopentadienyl)titanium(IV) dichloride and cyclopentadienyltitanium(IV) trichloride Martyn C. R. Symons and Shuddhodan P. Mishra, pp 2258 DOI:10.1039/DT9810002258 |
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The reactions of [Ru6C(CO)17] with dissolved and anchored phosphines. Crystal and molecular structure of [Ru6C(CO)16(PPh2Et)] Simon C. Brown, John Evans and Michael Webster, pp 2263 DOI:10.1039/DT9810002263 |
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Back cover J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100BX043 |
Issue 12
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Front cover J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100FX045 |
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Contents pages J. Chem. Soc., Dalton Trans. DOI:10.1039/DT98100FP051 |
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The single-crystal electronic and electron spin resonance spectra of copper(II) doped bis(2,2-bipyridyl)nitritozinc(II) nitrate and bis(2,2-bipyridyl)nitritocopper(II) tetrafluoroborate: a fluxional CuN2N2O2 chromophore William Fitzgerald, Brigid Murphy, Suresh Tyagi, Bernadette Walsh, Andrew Walsh and Brian Hathaway, pp 2271 DOI:10.1039/DT9810002271 |
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Reversible addition of protic molecules to co-ordinated di-2-pyridyl ketone in palladium(II), platinum(II), and gold(III) complexes. X-Ray crystal structures of dichloro(dihydroxy-di-2-pyridylmethane)palladium(II) and dichloro(dihydroxy-di-2-pyridylmethane)gold(III) chloride Giuliano Annibale, Luciano Canovese, Lucio Cattalini, Giovanni Natile, Marina Biagini-Cingi, Anna-Maria Manotti-Lanfredi and Antonio Tiripicchio, pp 2280 DOI:10.1039/DT9810002280 |
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Location of cations in metal ion-exchanged zeolites. Part 2. Crystal structures of a fully silver-exchanged heulandite Nevenka Bresciani-Pahor, Mario Calligaris, Giorgio Nardin and Lucio Randaccio, pp 2288 DOI:10.1039/DT9810002288 |
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Reactions of alkali-metal azides with some organophosphorus(V) compounds Keith B. Dillon, Andrew W. G. Platt and (the late) Thomas C. Waddington, pp 2292 DOI:10.1039/DT9810002292 |
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Tin-119 Mössbauer spectroscopic study of a single crystal of -SnF2 and partially oriented -PbSnF4 Thomas Birchall, George Dén  s, Krzysztof Ruebenbauer and Jean Pannetier,pp 2296 DOI:10.1039/DT9810002296 |
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Diagrams of existence of chloramines and bromamines in aqueous solution Michel Soulard, François Bloc and André Hatterer, pp 2300 DOI:10.1039/DT9810002300 |
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Photochemistry of methyl- and acetyl-dicarbonyl(-cyclopentadienyl)-iron in frozen gas matrices at 12 K. Infrared spectroscopic evidence for the formation of tricarbonyl(-cyclopentadienyl)methyliron and acetylmonocarbonyl(-cyclopentadienyl)iron David J. Fettes, Ramaier Narayanaswamy and Antony J. Rest, pp 2311 DOI:10.1039/DT9810002311 |
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Effect of organic groups on the carbonyl-insertion reaction of platinum(II) Ronald J. Cross and James Gemmill, pp 2317 DOI:10.1039/DT9810002317 |
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Reactions of co-ordinated ligands. Part 25. The synthesis of µ-allene-dicarbonylbis(5-indenyl)dirhodium and protonation to form a bridged cationic vinyl complex; molecular structures of µ-allene-dicarbonylbis(5-indenyl)dirhodium and dicarbonyl-bis(5-indenyl)-µ-(1-methylvinyl)-dirhodium(Rh-Rh) tetrafluoroborate Yassin N. Al-Obaidi, Paul K. Baker, Michael Green, Nicholas D. White and Graham E. Taylor, pp 2321 DOI:10.1039/DT9810002321 |
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Electron spin resonance spectra of a TiIV-TiIII mixed-valence tetranuclear species [Ti4(OR)12O] Sylviane Sabo, Robert Choukroun and Danièle Gervais, pp 2328 DOI:10.1039/DT9810002328 |
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Mechanisms of complex formation in the reactions of 1,2-dihydroxybenzene and 1,2-dihydroxy-4-methylbenzene with palladium(II) chloride and with aquapalladium(II), equilibria and kinetics in acid media John S. Coe and Edoardo Mentasti, pp 2331 DOI:10.1039/DT9810002331 |
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Pentamethylcyclopentadienyl-rhodium and -iridium complexes. Part 31. Tri-µ-phenoxo-rhodium complexes and a facile H/D exchange reaction Andrew Nutton and Peter M. Maitlis, pp 2335 DOI:10.1039/DT9810002335 |
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Pentamethylcyclopentadienyl-rhodium and -iridium complexes. Part 32. Reactions of tri-µ-hydroxo-complexes with aniline and aliphatic amines Andrew Nutton and Peter M. Maitlis, pp 2339 DOI:10.1039/DT9810002339 |
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Pentamethylcyclopentadienyl-rhodium and -iridium complexes. Part 33. The metal-catalysed disproportionation of acetaldehyde into acetic acid and ethanol John Cook, John E. Hamlin, Andrew Nutton and Peter M. Maitlis, pp 2342 DOI:10.1039/DT9810002342 |
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Studies on (-cyclo-octatetraene)(5-fluorenyl)titanium by electron spin resonance and electronic absorption spectroscopy Edmond Samuel, Gérard Labauze and Daniel Vivien, pp 2353 DOI:10.1039/DT9810002353 |
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Isolation of the anions [M(CO)5(SH)]- and [M2(CO)10(µ-SH)]-(M = Cr, Mo, and W) as salts of the sodium (18-crown-6-ether) cation. X-Ray analysis of the sodium carbonyl linked polymeric structures of the tungsten species Mervyn K. Cooper, Paul A. Duckworth, Kim Henrick and Mary McPartlin, pp 2357 DOI:10.1039/DT9810002357 |
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A study of substituent and base effects on the electron spin resonance spectra of the molecular oxygen adducts of cobalt(II) porphyrin chelates Ivan M. Ruzic, Thomas D. Smith and John R. Pilbrow, pp 2365 DOI:10.1039/DT9810002365 |
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Mechanism of water substitution in the trigonal-bipyramidal complex [Cu(tren)(OH2)]2+(tren = 2,2,2-triaminotriethylamine): evidence for an associative mechanism George R. Cayley, Iain D. Kelly, Peter F. Knowles and Kapil D. S. Yadav, pp 2370 DOI:10.1039/DT9810002370 |
Interpretation of bond-length data for transition-metal-acetylene complexes, in particular the complex [C5H5NH][TaCl4(PhC CPh)(NC5H5)]Edward A. Robinson, pp 2373 DOI:10.1039/DT9810002373 |
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Zirconium phosphates partially exchanged with transition-metal ions: characterisation and stereochemical changes induced by heat treatment Lucilla Alagna, Anthony A. G. Tomlinson, Carla Ferragina and Aldo La Ginestra, pp 2376 DOI:10.1039/DT9810002376 |
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Novel ligational behaviour of thiosalicylohydrazide and its derivatives with cobalt(II), nickel(II), copper(II), and palladium(II) Prasanta K. Biswas and Nirmalendu Ray Chaudhuri, pp 2385 DOI:10.1039/DT9810002385 |
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Reactions of acetylenes with noble-metal carbonyl halides. Part 4. The formation of a platinaoxacyclopentenone ring Franco Canziani, Luigi Garlaschelli, Maria C. Malatesta and Alberto Albinati, pp 2395 DOI:10.1039/DT9810002395 |
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Syntheses and characterization of the cyclopalladated complexes of benzyl butyl sulphides Yoshio Fuchita, Katsuma Hiraki, Takanori Yamaguchi and Takami Maruta, pp 2405 DOI:10.1039/DT9810002405 |
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Crystal structure of benzyltriphenylphosphonium pentachlorosulphido-tungstate(VI) and a study of the vibrational spectra of salts containing [WCl5Y]-(Y = O or S) ions Michael G. B. Drew, Gerald W. A. Fowles, Elizabeth M. Page and David A. Rice, pp 2409 DOI:10.1039/DT9810002409 |
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Evidence for contribution of intermediate steps to the limiting rate in iron(III) monomandelate complex formation F. Paolo Cavasino, Emanuele Di Dio and Carmelo Sbriziolo, pp 2414 DOI:10.1039/DT9810002414 |
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Phosphonate complexes. Part 5. An improved multiparametric refinement program, MUCOMP, for complex formation studies from potentiometric data Michel Wozniak, Joël Canonne and Guy Nowogrocki, pp 2419 DOI:10.1039/DT9810002419 |
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Phosphonate complexes. Part 6. Influence of steric effects, solvation, and chelation on stability Michel Wozniak and Guy Nowogrocki, pp 2423 DOI:10.1039/DT9810002423 |
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Kinetics and equilibria of reversible chelate ring-opening nucleophilic substitution reactions of [(o-dimethylaminophenyl)dimethylarsine]-rhodium(III) complexes Arnaldo Peloso, pp 2429 DOI:10.1039/DT9810002429 |
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Calorimetric titration studies of adduct formation between lanthanide -diketonates and organic bases in benzene solution Douglas P. Graddon and Lauraine Muir, pp 2434 DOI:10.1039/DT9810002434 |
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Nuclear magnetic resonance investigations of configurational non-rigidity in dinuclear platinum(IV) complexes. Part 4. Ring reversal, pyramidal inversion, and novel fluxional rearrangements in [(PtXMe3)2(MeSCH2SeMe)] complexes Edward W. Abel, Kenneth Kite, Keith G. Orrell, Vladimir ik and Bruce L. Williams,pp 2439 DOI:10.1039/DT9810002439 |
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A neutron diffraction investigation of the defect rutile structure of tin-antimony oxide Frank J. Berry and Colin Greaves, pp 2447 DOI:10.1039/DT9810002447 |
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Solvent isotope effects in the acidolysis and other electrophilic substitution reactions of penta-aquaorganochromium(III) ions in aqueous solution Victor Gold and David L. Wood, pp 2452 DOI:10.1039/DT9810002452 |
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Dialkyl sulphoxides as starting materials for the preparation of alkyl-transition-metal complexes. Formation of penta-aquamethylchromium(III) and pentacyanomethylcobaltate(III) salts, and the reduction of methyl radicals by vanadium(II) Victor Gold and David L. Wood, pp 2462 DOI:10.1039/DT9810002462 |
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Molecular structures of dimethylaluminium octahydrotriborate and dimethylgallium octahydrotriborate in the gas phase as determined by electron diffraction C. John Dain, Anthony J. Downs and David W. H. Rankin, pp 2465 DOI:10.1039/DT9810002465 |
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Chemistry of di- and tri-metal complexes with bridging carbene or carbyne ligands. Part 9. Reactivity of the cations [MPt(µ-CC6H4Me-4)(CO)2(PR3)2(-C5H5)]+(M = Mn or Re, Pr3= PMe3 or PMe2Ph) towards tertiary phosphines and the toluene-p-thiolate anion; X-ray crystal structures of [MnPt{µ-C(PMe3)C6H4Me-4}(CO)2(PMe3)2(-C5H5)][BF4] and [MnPt(SC6H4Me-4){µ-C(PMe3)C6H4Me-4}(µ-CO)(CO)(PMe3)(-C5H5)] John C. Jeffery, Rafael Navarro, Hayat Razay and F. Gordon A. Stone, pp 2471 DOI:10.1039/DT9810002471 |
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Esterification of amino-acids chelated to cobalt(III), molybdenocene, and platinum(II). Stability of chelated esters versus dechelation Henry Wautier, Viviane Daffe, Marie-Noëlle Smets and Jacques Fastrez, pp 2479 DOI:10.1039/DT9810002479 |
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CH-Acidity of amino-acid esters co-ordinated to cobalt(III). Racemization during the formation of peptides Henry Wautier, Daniel Marchal and Jacques Fastrez, pp 2484 DOI:10.1039/DT9810002484 |
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Kinetics of nucleophilic attack on co-ordinated organic moieties. Part 19. Addition of anilines to tricarbonyl(1-5--dienyl)iron cations Leon A. P. Kane-Maguire, Timothy I. Odiaka, Steve Turgoose and Peter A. Williams, pp 2489 DOI:10.1039/DT9810002489 |
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Synthesis and crystal structures of tetraethylammonium µ3-acetyl-C1-(Fe1Fe2)O(Fe1Fe3)-nonacarbonyl-triangulo-triferrate and tetraethyl-ammonium µ-carbonyl-nonacarbonyl-µ3-2,4-dioxapentylidyne-triangulo-triferrate Wai-Kwok Wong, Geoffrey Wilkinson, A. M. Galas, Michael B. Hursthouse and Mark Thornton-Pett, pp 2496 DOI:10.1039/DT9810002496 |
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Infrared and electronic spectra of matrix-isolated tetrafluoro- and tetrachloro-oxo-molybdenum(VI) and -oxotungsten(VI) and tetrabromo-oxo-tungsten(VI) William Levason, Ramaier Narayanaswamy, J. Steven Ogden, Antony J. Rest and Jeremy W. Turff, pp 2501 DOI:10.1039/DT9810002501 |
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Metal complexes of sulphur ligands. Part 21. Reactions of [Ru(SOCPh)2(PMe2Ph)2] with Ph2P(CH2)nPPh2(n= 1 or 2) and PMe2Ph and of cis-[RuCl2(PMe2Ph)4] with ammonium monothiobenzoate. Crystal and molecular structure of [Ru(SOCPh)2(PMe2Ph){Ph2P(CH2)2PPh2}]·MeOH Robert O. Gould, T. Anthony Stephenson and Mary A. Thomson, pp 2508 DOI:10.1039/DT9810002508 |
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Bonding in clusters. Part 3. Protonation of nido-pentaborane(9), nido-hexaborane(10), and closo-hexaborate(6)(2-) Paul Brint, Eamonn F. Healy, Trevor R. Spalding and Tom Whelan, pp 2515 DOI:10.1039/DT9810002515 |
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Preparation, properties, and crystal and molecular structures of bis(dialkylamine) complexes of rhenium(I) Fausto Calderazzo, Dario Vitali, Ishwerlal P. Mavani, Fabio Marchetti, Ivan Bernal, James D. Korp, Jerry L. Atwood, Robin D. Rogers and M. Susan Dalton, pp 2523 DOI:10.1039/DT9810002523 |
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Nuclear magnetic resonance and electronic spectral studies on the formation of -olefin-tetracyanocobaltate(I) complexes Takuzo Funabiki and Satohiro Yoshida, pp 2529 DOI:10.1039/DT9810002529 |
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Kinetics of the reaction between chlorite and hexacyanoferrate(II) in aqueous solution; evidence for an interfacial redox reaction Abbas H. Khan and William C. E. Higginson, pp 2537 DOI:10.1039/DT9810002537 |
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Spectrophotometric studies of the copper(II)-D-o-tyrosine complex. Assignment of the 330-nm dichroic band in copper(II) and iron(III) transferrins Arlette Garnier-Suillerot, Jean-Paul Albertini, André Collet, Liliane Faury, José-Maria Pastor and Lucia Tosi, pp 2544 DOI:10.1039/DT9810002544 |
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Reduction chemistry of hydrido(triethylphosphine) complexes of platinum(II) or palladium(II) and aqueous chemistry of tris(triethylphosphine)palladium(0) Rodney F. Jones, John R. Fisher and David J. Cole-Hamilton, pp 2550 DOI:10.1039/DT9810002550 |
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Structural and mechanistic studies of co-ordination compounds. Part 31. The chromium(II) reduction of some trans-tetra-aminedichloro-ruthenium(III) cations Chung-Kwong Poon, Tin-Wu Tang and Tai-Chu Lau, pp 2556 DOI:10.1039/DT9810002556 |
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Protonation and complex formation with heavy-metal ions of two tetrafunctional amines and of a new structurally related ion-exchange resin Rolando Barbucci, Mario Casolaro, M. Cristina Beni, Paolo Ferruti, Maria Pesavento, Teresa Soldi and Carla Riolo, pp 2559 DOI:10.1039/DT9810002559 |
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Solid-state absorption and circular-dichroism spectra of five-co-ordinate trigonal copper(II) complexes: anisotropic contributions to the d-d transition probabilities Reiko Kuroda, Stephen F. Mason, Tommaso Prosperi, Sonia Savage and George E. Tranter, pp 2565 DOI:10.1039/DT9810002565 |
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The chemistry of isomers of icosaborane(26), B20H26: synthesis and nuclear magnetic resonance study of various isomers of platinahenicosaboranes and diplatinadocosaboranes, and the X-ray crystal and molecular structures of 7,7-bis(dimethylphenylphosphine)-nido-7-platinaundecaborane and 4-(2-nido-decaboranyl)-7,7-bis(dimethylphenylphosphine)-nido-7-platinaundecaborane Simon K. Boocock, Norman N. Greenwood, John D. Kennedy, Walter S. McDonald and John Staves, pp 2573 DOI:10.1039/DT9810002573 |
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Notes. Activation of dioxygen and catalytic oxidation of ethanol to acetaldehyde and hydrogen peroxide by copper(I) complexes containing 2,2-bipyridyl and tertiary phosphine ligands Sumit Bhaduri and Niteen Y. Sapre, pp 2585 DOI:10.1039/DT9810002585 |
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The direct synthesis of alkali-metal pentafluoromanganates(III) Manabendra N. Bhattacharjee, Mihir K. Chaudhuri, Himadri S. Dasgupta and Darlando T. Khathing, pp 2587 DOI:10.1039/DT9810002587 |
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Influence of light on the oxidative addition of bromine to trans-[PtCl2-(PEt3)2]: crystal structure of all-trans-[PtBr2Cl2(PEt3)2] Subhi Al-Jibori, Christopher Crocker, Walter S. McDonald and Bernard L. Shaw, pp 2589 DOI:10.1039/DT9810002589 |
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A simple synthesis of cyclopentadienylindium(I) Clovis Peppe, Dennis G. Tuck and Luis Victoriano, pp 2592 DOI:10.1039/DT9810002592 |
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Synthesis and some reactions of the rhodacyclopentadiene complex [Rh(CO)2{C4(CO2Me)4Rh(CO)2PPh3)}] Brian L. Booth, Robert N. Haszeldine and Ian Perkins, pp 2593 DOI:10.1039/DT9810002593 |
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Calorimetric titration and hydrogen-1 nuclear magnetic resonance studies of adduct formation between cobalt(III)-diketonates and a lanthanide shift reagent Douglas P. Graddon, Lauraine Muir, Leonard F. Lindoy and Hon Way Louie, pp 2596 DOI:10.1039/DT9810002596 |
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Letters Ole Mønsted, Gwyneth Nord, R. D. Gillard and R. J. Wademan, pp 2599 DOI:10.1039/DT9810002599 |